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234826

Bis(cyclopentadienyl)titanium(IV) dichloride

Name: Bis(cyclopentadienyl)titanium(IV) dichloride
Brand: ALDRICH

97%

Synonym(s):

Cp2TiCl2, Dichlorobis(1,3-cyclopentadiene)titanium, Dichlorodicyclopentadienyltitanium, Dichlorotitanocene, Cp₂TiCl₂, Di(cyclopentadienyl)titanium(IV) dichloride, Titanocene dichloride

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About This Item

Empirical Formula (Hill Notation):

C₁₀H₁₀Cl₂Ti

CAS Number:

1271-19-8

Molecular Weight:

248.96

NACRES:

NA.22

PubChem Substance ID:

24854058

UNSPSC Code:

12161600

EC Number:

215-035-9

MDL number:

MFCD00003723

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Properties

Quality Level

100

assay

97%

reaction suitability

core: titanium, reagent type: catalyst

mp

260-280 °C (dec.) (lit.)

density

1.6 g/mL at 25 °C (lit.)

SMILES string

Cl[Ti]Cl.[CH]1[CH][CH][CH][CH]1.[CH]2[CH][CH][CH][CH]2

InChI

1S/2C5H5.2ClH.Ti/c2*1-2-4-5-3-1;;;/h2*1-5H;2*1H;/q;;;;+2/p-2

InChI key

XKLWATAZDMHTSH-UHFFFAOYSA-L

Description

Application

One-pot synthesis of α-methylene-γ-butyrolactones from benzaldehydes and bromomethylacrylates.

pictograms

GHS05,GHS07,GHS09

signalword

Danger

hcodes

H318,H335,H410

pcodes

P261 - P271 - P273 - P280 - P304 + P340 + P312 - P305 + P351 + P338

Hazard Classifications

Aquatic Acute 1 - Aquatic Chronic 1 - Eye Dam. 1 - STOT SE 3

target_organs

Respiratory system

Storage Class

11 - Combustible Solids

wgk

WGK 3

ppe

dust mask type N95 (US), Eyeshields, Gloves

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Synthesis, Ti(IV) intake by apotransferrin and cytotoxic properties of functionalized titanocene dichlorides.

Li Ming Gao et al.

Journal of biological inorganic chemistry : JBIC : a publication of the Society of Biological Inorganic Chemistry, 12(7), 959-967 (2007-06-15)

Functionalization of cyclopentadienyl (Cp) ligands and incorporation of these into a Ti(IV) center require careful design and selection of the appropriate synthetic routes to obtain the desired product in reasonably good yields. As part of our research efforts in the

Study of the cytotoxicity and particle action in human cancer cells of titanocene-functionalized materials with potential application against tumors.

Alberto García-Peñas et al.

Journal of inorganic biochemistry, 106(1), 100-110 (2011-11-25)

Titanocene dichloride [Ti(η(5)-C(5)H(5))(2)Cl(2)] (1), has been grafted onto dehydrated hydroxyapatite (HAP), Al(2)O(3) and two mesoporous silicas MSU-2 (Michigan State University Silica type 2) and HMS (Hexagonal Mesoporous Silica), to give the novel materials HAP/[Ti(η(5)-C(5)H(5))(2)Cl(2)] (S1) (1.01 wt.% Ti), Al(2)O(3)/[Ti(η(5)-C(5)H(5))(2)Cl(2)] (S2)

Pharmaceutical formulation affects titanocene transferrin interactions.

Katherine M Buettner et al.

Dalton transactions (Cambridge, England : 2003), 40(37), 9580-9588 (2011-08-19)

Since the discovery of the anticancer activity of titanocene dichloride (TDC), many derivatives have been developed and evaluated. MKT4, a soluble, water-stable formulation of TDC, was used for both Phase I and Phase II human clinical trials. This formulation is

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Global Trade Item Number

SKU	GTIN
234826-50G	04061838784711
234826-10G	04061838784704