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Merck
CN

234834

Cyclopentadienyltitanium(IV) trichloride

97%, solid

Synonym(s):

CpTiCl3

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About This Item

Empirical Formula (Hill Notation):
C5H5Cl3Ti
CAS Number:
Molecular Weight:
219.32
UNSPSC Code:
12161600
PubChem Substance ID:
NACRES:
NA.22
MDL number:
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Product Name

Cyclopentadienyltitanium(IV) trichloride, 97%

Quality Level

assay

97%

form

solid

reaction suitability

core: titanium, reagent type: catalyst

mp

210 °C (dec.) (lit.)

SMILES string

Cl[Ti](Cl)Cl.[CH]1[CH][CH][CH][CH]1

InChI

1S/C5H5.3ClH.Ti/c1-2-4-5-3-1;;;;/h1-5H;3*1H;/q;;;;+3/p-3

InChI key

AENCLWKVWIIOQH-UHFFFAOYSA-K

Application

Precusor for cyclopentadienyltitanium(IV) complexes, and used as catalysts for alkene polymerizations


pictograms

Corrosion

signalword

Danger

hcodes

Hazard Classifications

Eye Dam. 1 - Skin Corr. 1B

Storage Class

8A - Combustible corrosive hazardous materials

wgk

WGK 3

flash_point_f

Not applicable

flash_point_c

Not applicable

ppe

Eyeshields, Faceshields, Gloves, type P3 (EN 143) respirator cartridges



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David Hermann Lamparelli et al.
Polymers, 11(4) (2019-04-19)
The direct synthesis of syndiotactic polystyrene-block-polyethylene copolymer (sPS-b-PE) with a diblock structure has been achieved. The synthetic strategy consists of the sequential stereocontrolled polymerization of styrene and ethylene in the presence of a single catalytic system: cyclopentadienyltitanium(IV) trichloride activated by
McGrane, P. L.; Jensen, M. et al.
Journal of the American Chemical Society, 114, 5459-5459 (1992)
Erker, G.; Aulbach, M. et al.
Journal of the American Chemical Society, 115, 4590-4590 (1993)



Global Trade Item Number

SKUGTIN
234834-1G04061838784728
234834-5G04061833320785