235148
Tris(trimethylsiloxy)ethylene
95%
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About This Item
Linear Formula:
[(CH3)3SiO]2C=CHOSi(CH3)3
CAS Number:
Molecular Weight:
292.59
UNSPSC Code:
12352100
NACRES:
NA.22
PubChem Substance ID:
EC Number:
273-864-1
Beilstein/REAXYS Number:
1962905
MDL number:
Assay:
95%
Form:
liquid
InChI key
FCZGHPGTZRTDNN-UHFFFAOYSA-N
InChI
1S/C11H28O3Si3/c1-15(2,3)12-10-11(13-16(4,5)6)14-17(7,8)9/h10H,1-9H3
SMILES string
C[Si](C)(C)O\C=C(\O[Si](C)(C)C)O[Si](C)(C)C
assay
95%
form
liquid
Quality Level
bp
54-56 °C/0.1 mmHg (lit.)
density
0.886 g/mL at 25 °C (lit.)
storage temp.
2-8°C
Related Categories
Application
Tris(trimethylsiloxy)ethylene has been used in:
- stereospecific synthesis of insecticide ajuqarin-IV
- microwave-assisted synthesis of 2-hydroxy-1-phenylethanone
signalword
Warning
hcodes
Hazard Classifications
Eye Irrit. 2 - Flam. Liq. 3 - Skin Irrit. 2 - STOT SE 3
target_organs
Respiratory system
Storage Class
3 - Flammable liquids
wgk
WGK 3
flash_point_f
136.4 °F - closed cup
flash_point_c
58 °C - closed cup
ppe
Eyeshields, Gloves, type ABEK (EN14387) respirator filter
Regulatory Information
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Stereospecific total synthesis of ajugarin-IV.
Kende AS, et al.
Tetrahedron Letters, 23(17), 1751-1754 (1982)
Multienzymatic preparation of 3-[(1R)-1-hydroxyethyl] benzoic acid and (2< i> S</i>)-hydroxy (phenyl) ethanoic acid.
Gennaro PD, et al.
Tetrahedron Asymmetry, 21(15), 1885-1889 (2010)
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