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235202

4-Bromomethyl-7-methoxycoumarin

Name: 4-Bromomethyl-7-methoxycoumarin
Brand: ALDRICH

97%

Synonym(s):

BMC, Br-Mmc

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About This Item

Empirical Formula (Hill Notation):

C₁₁H₉BrO₃

CAS Number:

35231-44-8

Molecular Weight:

269.09

UNSPSC Code:

12352100

NACRES:

NA.22

PubChem Substance ID:

24854087

EC Number:

252-448-3

Beilstein/REAXYS Number:

187211

MDL number:

MFCD00006869

Assay:

97%

Form:

solid

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Properties

Quality Level

200

assay

97%

form

solid

mp

213-215 °C (lit.)

solubility

chloroform: soluble 20 mg/mL, clear, colorless to faintly yellow

fluorescence

λ_ex 322 nm; λ_em 395 nm (after derivatization)

functional group

bromo, ester

SMILES string

COc1ccc2C(CBr)=CC(=O)Oc2c1

InChI

1S/C11H9BrO3/c1-14-8-2-3-9-7(6-12)4-11(13)15-10(9)5-8/h2-5H,6H2,1H3

InChI key

CTENSLORRMFPDH-UHFFFAOYSA-N

Description

Application

4-Bromomethyl-7-methoxycoumarin has been used:

as derivatization reagent in determination of 5-fluorouracil (5-FU) in human plasma by HPLC-tandem mass spectrometry
as derivatization reagent in fluorescence detection of sodium monofluoroacetate (MFA-Na) in biological samples by HPLC
in the synthesis of new caged derivatives of hydrolysis-resistant 8-bromoadenosine cyclic 3′,5′-monophosphate (8-Br-cAMP) and 8-bromoguanosine cyclic 3′,5′-monophosphate (8-Br-cGMP)
in TLC and HPLC separation and fluorometric analysis of a wide range of naturally occurring acids, including bile and thromboxane B₂

Fluorescent label for fatty acids.

pictograms

GHS07

signalword

Warning

hcodes

H302,H315,H319,H335

pcodes

P261 - P264 - P270 - P301 + P312 - P302 + P352 - P305 + P351 + P338

Hazard Classifications

Acute Tox. 4 Oral - Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3

target_organs

Respiratory system

Storage Class

11 - Combustible Solids

wgk

WGK 3

flash_point_f

Not applicable

flash_point_c

Not applicable

ppe

dust mask type N95 (US), Eyeshields, Gloves

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Journal of photochemistry and photobiology. B, Biology, 53(1-3), 91-102 (2000-02-15)

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Global Trade Item Number

SKU	GTIN
235202-5G	04061832242040
235202-1G	04061825752839