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About This Item
Linear Formula:
LiAlH4
CAS Number:
Molecular Weight:
37.95
MDL number:
UNSPSC Code:
26111700
PubChem Substance ID:
NACRES:
NA.22
form
liquid
Quality Level
reaction suitability
reagent type: reductant
concentration
0.5 M in 2-methoxyethyl ether
density
0.95 g/mL at 25 °C
storage temp.
2-30°C
SMILES string
[Li+].[AlH4-]
InChI
1S/Al.Li.4H/q-1;+1;;;;
InChI key
OCZDCIYGECBNKL-UHFFFAOYSA-N
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Related Categories
Application
Reactant or reagent for:
LAH is a powerful reducing agent for many different reduction reactions such as that of ketones to alcohols
- The preparation of thermoplastic polyester polyamides from oleic acid
- Lithium-polymer batteries
- Hydrodefluorination of gem-difluoromethylene derivatives
- Asymmetric aldol reactions
- Synthesis of Li-Al-N-H composites with hydrogen absorption / desorption properties
LAH is a powerful reducing agent for many different reduction reactions such as that of ketones to alcohols
Signal Word
Danger
Hazard Statements
Precautionary Statements
Hazard Classifications
Eye Irrit. 2 - Flam. Liq. 3 - Repr. 1B - Skin Irrit. 2 - Water-react 1
Supplementary Hazards
Storage Class Code
4.3 - Hazardous materials which set free flammable gases upon contact with water
WGK
WGK 3
Flash Point(F)
98.6 °F - closed cup
Flash Point(C)
37 °C - closed cup
Regulatory Information
危险化学品
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Lithium Aluminum Hydride.
eEROS (Encyclopedia of Reagents for Organic Synthesis), 126(3), 989-992 (2001)
Enhanced performance in lithium-polymer batteries using surface-functionalized Si nanoparticle anodes and self-assembled block copolymer electrolytes.
Choi, Ilyoung and Ahn, Hyungmin and Park, Moon Jeong
Macromolecules, 44(18), 7327-7334 (2011)
Solid Acids as Heterogeneous Support for Primary Amino Acid-Derived Diamines in Direct Asymmetric Aldol Reactions.
Demuynck ALW, et al.
Advanced Synthesis & Catalysis, 353(5), 725-732 (2011)
Thermoplastic polyester amides derived from oleic acid.
Zuo, Jiaqing and Li, Shaojun and Bouzidi, Laziz and Narine, Suresh S
Polymer, 52(20), 4503-4516 (2011)
ZnCl2-catalyzed hydrodefluorination of gem-difluoromethylene derivatives with lithium aluminum hydride.
Cheng, Jianhang and Wu, Jingjing and Cao, Song
Tetrahedron Letters, 52(27), 3481-3484 (2011)
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