Skip to Content
Merck
CN

237116

Bis(triphenylphosphine)nickel(II) dichloride

synthesis grade, solid

Synonym(s):

NiCl2(PPh3)2, Dichlorobis(triphenylphosphine)nickel(II), Nickel(II)bis(triphenylphosphine) dichloride

Sign In to View Organizational & Contract Pricing.

Select a Size


About This Item

Linear Formula:
[(C6H5)3P]2NiCl2
CAS Number:
Molecular Weight:
654.17
NACRES:
NA.22
PubChem Substance ID:
UNSPSC Code:
12161600
EC Number:
238-154-8
MDL number:
Technical Service
Need help? Our team of experienced scientists is here for you.
Let Us Assist
Technical Service
Need help? Our team of experienced scientists is here for you.
Let Us Assist

Product Name

Bis(triphenylphosphine)nickel(II) dichloride, synthesis grade

InChI key

ZBRJXVVKPBZPAN-UHFFFAOYSA-L

InChI

1S/2C18H15P.2ClH.Ni/c2*1-4-10-16(11-5-1)19(17-12-6-2-7-13-17)18-14-8-3-9-15-18;;;/h2*1-15H;2*1H;/q;;;;+2/p-2

SMILES string

Cl[Ni]Cl.c1ccc(cc1)P(c2ccccc2)c3ccccc3.c4ccc(cc4)P(c5ccccc5)c6ccccc6

grade

synthesis grade

form

solid

reaction suitability

core: nickel
reagent type: catalyst

mp

250 °C (dec.) (lit.)

Quality Level

Looking for similar products? Visit Product Comparison Guide

Application

Catalyst in the coupling reaction of aryl mesylates and allylic carbonates with lithium organoborates.

pictograms

Health hazardExclamation mark

signalword

Danger

Hazard Classifications

Aquatic Chronic 3 - Carc. 1B - Skin Sens. 1

Storage Class

6.1C - Combustible acute toxic Cat.3 / toxic compounds or compounds which causing chronic effects

wgk

WGK 3

flash_point_f

Not applicable

flash_point_c

Not applicable

ppe

dust mask type N95 (US), Eyeshields, Faceshields, Gloves, type P2 (EN 143) respirator cartridges


Choose from one of the most recent versions:

Certificates of Analysis (COA)

Lot/Batch Number

Don't see the Right Version?

If you require a particular version, you can look up a specific certificate by the Lot or Batch number.

Already Own This Product?

Find documentation for the products that you have recently purchased in the Document Library.

Visit the Document Library

Tetrahedron Letters, 37, 8531-8531 (1996)
Journal of the Chemical Society. Chemical Communications, 1789-1789 (1994)

Articles

Nickel complexes catalyze various synthetic reactions like oxidative addition, C-H activation, and cross-coupling.

Our team of scientists has experience in all areas of research including Life Science, Material Science, Chemical Synthesis, Chromatography, Analytical and many others.

Contact Technical Service