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237116

Bis(triphenylphosphine)nickel(II) dichloride

synthesis grade, solid

Synonym(s):

NiCl2(PPh3)2, Dichlorobis(triphenylphosphine)nickel(II), Nickel(II)bis(triphenylphosphine) dichloride

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About This Item

Linear Formula:
[(C6H5)3P]2NiCl2
CAS Number:
14264-16-5
Molecular Weight:
654.17
NACRES:
NA.22
PubChem Substance ID:
24854218
UNSPSC Code:
12161600
EC Number:
238-154-8
MDL number:
MFCD00009592
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Product Name

Bis(triphenylphosphine)nickel(II) dichloride, synthesis grade

grade

synthesis grade

Quality Level

100

form

solid

reaction suitability

core: nickel, reagent type: catalyst

mp

250 °C (dec.) (lit.)

SMILES string

Cl[Ni]Cl.c1ccc(cc1)P(c2ccccc2)c3ccccc3.c4ccc(cc4)P(c5ccccc5)c6ccccc6

InChI

1S/2C18H15P.2ClH.Ni/c2*1-4-10-16(11-5-1)19(17-12-6-2-7-13-17)18-14-8-3-9-15-18;;;/h2*1-15H;2*1H;/q;;;;+2/p-2

InChI key

ZBRJXVVKPBZPAN-UHFFFAOYSA-L

Application

Catalyst in the coupling reaction of aryl mesylates and allylic carbonates with lithium organoborates.

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pictograms

Health hazardExclamation mark
GHS08,GHS07

signalword

Danger

Hazard Classifications

Aquatic Chronic 3 - Carc. 1B - Skin Sens. 1

Storage Class

6.1C - Combustible acute toxic Cat.3 / toxic compounds or compounds which causing chronic effects

wgk

WGK 3

flash_point_f

Not applicable

flash_point_c

Not applicable

ppe

dust mask type N95 (US), Eyeshields, Faceshields, Gloves, type P2 (EN 143) respirator cartridges

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Certificates of Analysis (COA)

Lot/Batch Number
MKCX4939
MKCW8076
MKCV7047
MKCS1100
MKCS1116

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Articles

Nickel-based Catalysts

Nickel complexes catalyze various synthetic reactions like oxidative addition, C-H activation, and cross-coupling.

Tetrahedron Letters, 37, 8531-8531 (1996)
Journal of the Chemical Society. Chemical Communications, 1789-1789 (1994)

Global Trade Item Number

SKUGTIN
237116-10G04061838785978
237116-50G04061833545546