240761
1-Hexene
≥99%
Synonym(s):
1-n-Hexene
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About This Item
Linear Formula:
CH3(CH2)3CH=CH2
CAS Number:
Molecular Weight:
84.16
UNSPSC Code:
12352100
NACRES:
NA.22
PubChem Substance ID:
EC Number:
209-753-1
Beilstein/REAXYS Number:
1209240
MDL number:
Product Name
1-Hexene, ≥99%
InChI key
LIKMAJRDDDTEIG-UHFFFAOYSA-N
InChI
1S/C6H12/c1-3-5-6-4-2/h3H,1,4-6H2,2H3
SMILES string
CCCCC=C
vapor density
3 (vs air)
vapor pressure
155 mmHg ( 21.1 °C)
assay
≥99%
form
liquid
autoignition temp.
487 °F
refractive index
n20/D 1.388 (lit.)
bp
60-66 °C (lit.)
density
0.678 g/mL at 25 °C (lit.)
functional group
allyl
Quality Level
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Application
- 1-Hexene in High Molecular Weight Polymer Synthesis: The synthesis of high molecular weight copolymers from 1-hexene and methyl acrylate using Lewis acid catalysts showcased advanced applications in materials science, specifically in developing durable and versatile polymer materials (Wan et al., 2024).
- 1-Hexene′s Role in Proton-Exchange Membrane Enhancement: Utilizing 1-hexene in the structural characterization and enhancement of physicochemical properties of functionally porous proton-exchange membranes highlights its critical role in improving energy efficiency and performance in fuel cell technologies (Ponomar et al., 2024).
General description
The kinetics of polymerization of 1-hexene was studied using a family of five zirconium amine bis-phenolate catalysts. Polymerization reaction of 1-hexene catalyzed by a series of hafnium complexes was studied.
signalword
Danger
hcodes
Hazard Classifications
Asp. Tox. 1 - Flam. Liq. 2
supp_hazards
Storage Class
3 - Flammable liquids
wgk
WGK 2
flash_point_f
-13.0 °F - closed cup
flash_point_c
-25.0 °C - closed cup
ppe
Eyeshields, Faceshields, Gloves, type ABEK (EN14387) respirator filter
Regulatory Information
危险化学品
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Lingyan Gong et al.
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Dalton transactions (Cambridge, England : 2003), 42(25), 9120-9128 (2012-12-14)
Non-bridged half-metallocene dimethyl complexes of group 4 metals 2a-4a with an N-4-methoxyphenyl(iminomethyl)pyrrolyl ligand 1a were synthesized and characterized by NMR spectroscopy and X-ray analysis. Upon activation with [Ph3C][B(C6F5)4], these complexes became active catalysts for the polymerization of 1-hexene. A series
D Keith Steelman et al.
Journal of the American Chemical Society, 135(16), 6280-6288 (2013-03-23)
The kinetics of 1-hexene polymerization using a family of five zirconium amine bis-phenolate catalysts, Zr[tBu-ON(X)O]Bn2 (where X = THF (1), pyridine (2), NMe2 (3), furan (4), and SMe (5)), has been investigated to uncover the mechanistic effect of varying the
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Journal of the American Chemical Society, 137(21), 6965-6971 (2015-05-12)
The stereochemistry, kinetics, and mechanism of olefin polymerization catalyzed by a set of zirconium-based metallocenes was studied by NMR using dissolution dynamic nuclear polarization (DNP). Hyperpolarized 1-hexene was polymerized in situ with a C2 symmetric catalyst, [(EBI)ZrMe][B(C6F5)4] (EBI = rac-(C2H4(1-indenyl)2))
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