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Merck
CN

240915

2,4-Dimethylaniline

≥99%

Synonym(s):

1-Amino-2,4-dimethylbenzene, 2,4-Xylidine, 4-Amino-m-xylene

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About This Item

Linear Formula:
(CH3)2C6H3NH2
CAS Number:
95-68-1
Molecular Weight:
121.18
UNSPSC Code:
12352100
NACRES:
NA.22
PubChem Substance ID:
24854443
EC Number:
202-440-0
Beilstein/REAXYS Number:
636243
MDL number:
MFCD00007738
Assay:
≥99%
Form:
liquid

Key Documents

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InChI key

CZZZABOKJQXEBO-UHFFFAOYSA-N

InChI

1S/C8H11N/c1-6-3-4-8(9)7(2)5-6/h3-5H,9H2,1-2H3

SMILES string

Cc1ccc(N)c(C)c1

vapor density

4.2 (vs air)

vapor pressure

0.16 mmHg ( 25 °C)

assay

≥99%

form

liquid

autoignition temp.

860 °F

expl. lim.

7 %

Quality Level

100

bp

218 °C (lit.)

mp

−14.3 °C (lit.)

density

0.98 g/mL at 25 °C (lit.)

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General description

2,4-Dimethylaniline, the final degradation product of the pesticide amitraz, was measured by cyclic voltammetry.

signalword

Danger

Hazard Classifications

Acute Tox. 3 Dermal - Acute Tox. 3 Inhalation - Acute Tox. 3 Oral - Aquatic Chronic 2 - STOT RE 2

Storage Class

6.1A - Combustible acute toxic Cat. 1 and 2 / very toxic hazardous materials

wgk

WGK 3

flash_point_f

208.4 °F - closed cup

flash_point_c

98 °C - closed cup

ppe

Eyeshields, Faceshields, Gloves, type ABEK (EN14387) respirator filter

Regulatory Information

危险化学品
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Certificates of Analysis (COA)

Lot/Batch Number
0000461484
0000461484
0000446146
0000446146
0000290156

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C Gopinath et al.
Toxicology, 15(2), 113-127 (1980-01-01)
The usefulness of measuring serum bile acid concentrations by RIA in a number of acute experimental liver injuries of rats was assessed by comparing the concentrations with the results of some of the routinely employed methods of examining hepatotoxic changes.
Ee Lui Ang et al.
Applied microbiology and biotechnology, 81(6), 1063-1070 (2008-09-25)
The objective of this study was to enhance the activity of aniline dioxygenase (AtdA), a multi-component Rieske non-heme iron dioxygenase enzyme isolated from Acinetobacter sp. strain YAA, so as to create an enhanced biocatalyst for the bioremediation of aromatic amines.
Jin-Zhong Xu et al.
Journal of separation science, 32(23-24), 4020-4024 (2010-01-13)
A method for the determination and confirmation of amitraz and its degradation product 2,4-dimethylaniline (2,4-DMA) in honey is reported. Determination of the two compounds was based on HPLC with UV detection and MS/MS (LC-MS/MS) after a liquid-liquid extraction with hexane
O Osano et al.
Archives of environmental contamination and toxicology, 43(1), 42-49 (2002-06-05)
Developmental effects of amitraz (acaricide), its metabolite (2,4-dimethylaniline), and paraquat (herbicide) on embryos of a nontarget organism, Xenopus laevis, were investigated. Following the standard protocol of the American Society for Testing and Materials (ASTM), the experiments were carried out using
Stefan H Bossmann et al.
Chemphyschem : a European journal of chemical physics and physical chemistry, 3(5), 401-407 (2002-12-06)
TiO2-codoped [FeII(bpy)3]2+/zeolite Y systems are revealed to be efficient photocatalysts for photochemically enhanced Fenton processes. Preparation, characterization, and tests using 2,4-xylidine as a model pollutant are described, and a first mechanistic hypothesis explaining the rather high photochemical reactivity of the
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