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Merck
CN

242861

Chloroiodomethane

97%

Synonym(s):

Chloromethyl iodide, Iodochloromethane

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About This Item

Linear Formula:
ClCH2I
CAS Number:
593-71-5
Molecular Weight:
176.38
UNSPSC Code:
12352100
NACRES:
NA.22
PubChem Substance ID:
24854589
EC Number:
209-804-8
Beilstein/REAXYS Number:
1730802
MDL number:
MFCD00001078

Key Documents

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Product Name

Chloroiodomethane, 97%

InChI key

PJGJQVRXEUVAFT-UHFFFAOYSA-N

InChI

1S/CH2ClI/c2-1-3/h1H2

SMILES string

ClCI

assay

97%

form

liquid

contains

copper as stabilizer

refractive index

n20/D 1.582 (lit.)

bp

108-109 °C (lit.)

density

2.422 g/mL at 25 °C (lit.)

functional group

chloro
iodo

Quality Level

100

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General description

The photolysis of chloroiodomethane in cryogenic matrices along with recombination of the nascent radical pair was studied.

pictograms

Skull and crossbones
GHS06

signalword

Danger

Hazard Classifications

Acute Tox. 3 Oral - Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3

target_organs

Respiratory system

Storage Class

6.1C - Combustible acute toxic Cat.3 / toxic compounds or compounds which causing chronic effects

wgk

WGK 3

flash_point_f

Not applicable

flash_point_c

Not applicable

ppe

Eyeshields, Gloves, type ABEK (EN14387) respirator filter

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Certificates of Analysis (COA)

Lot/Batch Number
WXBF3268V
WXBD7743V
WXBD5213V
WXBD4420V
WXBD2196V

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Andrew J Sumner et al.
Environmental science & technology, 53(14), 8216-8226 (2019-07-06)
A number of flowback samples derived from horizontally drilled hydraulic fracturing (HDHF) operations reveal consistent detections of halogenated organic species , yet the source of these compounds remains uncertain. Studies simulating subsurface conditions have found that oxidative "breakers" can halogenate certain
Thomas J Preston et al.
The Journal of chemical physics, 135(11), 114503-114503 (2011-09-29)
Photolysis of chloroiodomethane (CH(2)ClI) in cryogenic matrices followed by recombination of the nascent radical pair produces an isomer (CH(2)Cl-I) that features a halogen-halogen (Cl-I) bond. Using ultrafast laser pulses, it is possible to follow the formation of this isomer by

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