243965
Phenylselenyl bromide
98%
Synonym(s):
Benzeneselenenyl bromide, Benzeneselenyl bromide
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About This Item
Linear Formula:
C6H5SeBr
CAS Number:
Molecular Weight:
235.97
UNSPSC Code:
12352100
NACRES:
NA.22
PubChem Substance ID:
EC Number:
252-238-1
Beilstein/REAXYS Number:
2039772
MDL number:
Assay:
98%
Form:
solid
Quality Level
assay
98%
form
solid
bp
107-108 °C/15 mmHg (lit.)
mp
58-62 °C (lit.)
SMILES string
Br[Se]c1ccccc1
InChI
1S/C6H5BrSe/c7-8-6-4-2-1-3-5-6/h1-5H
InChI key
LCEFEIBEOBPPSJ-UHFFFAOYSA-N
Application
Phenylselenyl bromide was used in the preparation of exo-2-methyl-7-phenylselenyl-octahydro-8-oxa-2,7b-diaza-dicyclopenta[a,e]pentalene-1,3-dione and endo-2-methyl-7-phenylselanyl-octahydro-8-oxa-2,7b-diaza-dicyclopenta[a,e]pentalene-1,3-dione. It was also used in the synthesis of enones by selenenylation of α-cyano ketones with lithium naphthalenide.
signalword
Danger
Hazard Classifications
Acute Tox. 3 Inhalation - Acute Tox. 3 Oral - Aquatic Acute 1 - Aquatic Chronic 1 - Met. Corr. 1 - STOT RE 2
Storage Class
6.1A - Combustible acute toxic Cat. 1 and 2 / very toxic hazardous materials
wgk
WGK 3
flash_point_f
Not applicable
flash_point_c
Not applicable
ppe
Eyeshields, Faceshields, Gloves, type P2 (EN 143) respirator cartridges
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X= Y?ZH Systems as potential 1, 3-dipoles. Part 52: Fused-ring forming electrophile induced oxime→nitrone→ cycloaddition cascades.
Ali Dondas H, et al.
Tetrahedron Letters, 57(32), 7035-7045 (2001)
Synlett, 1274-1274 (2007)
Santanu Hati et al.
European journal of medicinal chemistry, 100, 188-196 (2015-06-19)
Herein we have reported design, synthesis and in vitro biological evaluation of a library of bicyclic lactams that led to the discovery of compounds 6 and 7 as a novel class of α-glucosidase inhibitors. They inhibited α-glucosidase (yeast origin) in a
Global Trade Item Number
| SKU | GTIN |
|---|---|
| 243965-25G | 04061825656571 |
| 243965-5G | 04061833498798 |