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Merck
CN

244430

3-Hexyn-1-ol

98%

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About This Item

Linear Formula:
C2H5C≡CCH2CH2OH
CAS Number:
Molecular Weight:
98.14
NACRES:
NA.22
PubChem Substance ID:
UNSPSC Code:
12352100
EC Number:
213-685-8
MDL number:
Assay:
98%
Form:
liquid
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Product Name

3-Hexyn-1-ol, 98%

InChI key

ODEHKVYXWLXRRR-UHFFFAOYSA-N

InChI

1S/C6H10O/c1-2-3-4-5-6-7/h7H,2,5-6H2,1H3

SMILES string

CCC#CCCO

assay

98%

form

liquid

refractive index

n20/D 1.454 (lit.)

bp

63-64 °C/12 mmHg (lit.)

density

0.898 g/mL at 25 °C (lit.)

functional group

hydroxyl

Quality Level

General description

The stereoselective hydrogenation of 3-hexyn-1-ol was studied. Poly(N-vinyl-2-pyrrolidone)-stabilized Pd-nanoclusters showed an extraordinary catalytic performance in the selective hydrogenation of 3-hexyn-1-ol.

pictograms

Exclamation mark

signalword

Warning

Hazard Classifications

Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3

target_organs

Respiratory system

Storage Class

10 - Combustible liquids

wgk

WGK 3

flash_point_f

145.4 °F - closed cup

flash_point_c

63 °C - closed cup

ppe

Eyeshields, Gloves, type ABEK (EN14387) respirator filter


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Jules C A A Roelofs et al.
Chemical communications (Cambridge, England), (8)(8), 970-971 (2004-04-08)
Poly(N-vinyl-2-pyrrolidone)-stabilized Pd-nanoclusters, for the first time exclusively supported on the hydrotalcite lateral surface, showed a remarkable catalytic performance in the selective hydrogenation of 3-hexyn-1-ol, which can be ascribed to both the influence of the protecting polymer PVP as well as
Alexander Sachse et al.
Dalton transactions (Cambridge, England : 2003), 42(5), 1378-1384 (2012-10-12)
Well-dispersed Pd nanoparticles have been synthesized inside the mesoporosity of a silica monolith featuring hierarchical porosity of homogeneous interconnected macropores (4 microns) and mesopores (11 nm). These monoliths have been implemented as microreactors for selective hydrogenation reactions. Conversion and selectivity
Shigeru Tamogami et al.
FEBS letters, 589(3), 390-395 (2015-01-13)
The medicinal herbal plant Achyranthes bidentata (A. bidentata) produces the sweet-odor ester - methyl (E)-2-hexenoate (1) as the major volatile in response to methyl jasmonate (MeJA). Here, we investigated the biosynthetic pathway of methyl (E)-2-hexenoate (1). The common plant precursor

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