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244430

3-Hexyn-1-ol

Name: 3-Hexyn-1-ol
Brand: ALDRICH

98%

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About This Item

Linear Formula:

C₂H₅C≡CCH₂CH₂OH

CAS Number:

1002-28-4

Molecular Weight:

98.14

NACRES:

NA.22

PubChem Substance ID:

24854676

UNSPSC Code:

12352100

EC Number:

213-685-8

MDL number:

MFCD00002957

Assay:

98%

Form:

liquid

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Properties

Quality Level

100

assay

98%

form

liquid

refractive index

n20/D 1.454 (lit.)

bp

63-64 °C/12 mmHg (lit.)

density

0.898 g/mL at 25 °C (lit.)

functional group

hydroxyl

SMILES string

CCC#CCCO

InChI

1S/C6H10O/c1-2-3-4-5-6-7/h7H,2,5-6H2,1H3

InChI key

ODEHKVYXWLXRRR-UHFFFAOYSA-N

Description

General description

The stereoselective hydrogenation of 3-hexyn-1-ol was studied. Poly(N-vinyl-2-pyrrolidone)-stabilized Pd-nanoclusters showed an extraordinary catalytic performance in the selective hydrogenation of 3-hexyn-1-ol.

pictograms

GHS07

signalword

Warning

hcodes

H315,H319,H335

pcodes

P261 - P264 - P271 - P280 - P302 + P352 - P305 + P351 + P338

Hazard Classifications

Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3

target_organs

Respiratory system

Storage Class

10 - Combustible liquids

wgk

WGK 3

flash_point_f

145.4 °F - closed cup

flash_point_c

63 °C - closed cup

ppe

Eyeshields, Gloves, type ABEK (EN14387) respirator filter

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Selective hydrogenation over Pd nanoparticles supported on a pore-flow-through silica monolith microreactor with hierarchical porosity.

Alexander Sachse et al.

Dalton transactions (Cambridge, England : 2003), 42(5), 1378-1384 (2012-10-12)

Well-dispersed Pd nanoparticles have been synthesized inside the mesoporosity of a silica monolith featuring hierarchical porosity of homogeneous interconnected macropores (4 microns) and mesopores (11 nm). These monoliths have been implemented as microreactors for selective hydrogenation reactions. Conversion and selectivity

First example of high loaded polymer-stabilized nanoclusters immobilized on hydrotalcite: effects in alkyne hydrogenation.

Jules C A A Roelofs et al.

Chemical communications (Cambridge, England), (8)(8), 970-971 (2004-04-08)

Poly(N-vinyl-2-pyrrolidone)-stabilized Pd-nanoclusters, for the first time exclusively supported on the hydrotalcite lateral surface, showed a remarkable catalytic performance in the selective hydrogenation of 3-hexyn-1-ol, which can be ascribed to both the influence of the protecting polymer PVP as well as

Methyl jasmonate elicits the production of methyl (E)-2-hexenoate from (Z)-2-hexenol via (Z)-2-hexenal in Achyranthes bidentata plant.

Shigeru Tamogami et al.

FEBS letters, 589(3), 390-395 (2015-01-13)

The medicinal herbal plant Achyranthes bidentata (A. bidentata) produces the sweet-odor ester - methyl (E)-2-hexenoate (1) as the major volatile in response to methyl jasmonate (MeJA). Here, we investigated the biosynthetic pathway of methyl (E)-2-hexenoate (1). The common plant precursor

Global Trade Item Number

SKU	GTIN
244430-25G	04061825759944