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Merck
CN

245798

2-Iodo-2-methylpropane

contains copper as stabilizer, 95%

Synonym(s):

tert-Butyl iodide

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About This Item

Linear Formula:
(CH3)3Cl
CAS Number:
558-17-8
Molecular Weight:
184.02
UNSPSC Code:
12352100
NACRES:
NA.22
PubChem Substance ID:
24854758
MDL number:
MFCD00001068
Beilstein/REAXYS Number:
505950
Assay:
95%
Form:
liquid

Key Documents

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Product Name

2-Iodo-2-methylpropane, contains copper as stabilizer, 95%

InChI

1S/C4H9I/c1-4(2,3)5/h1-3H3

SMILES string

CC(C)(C)I

InChI key

ANGGPYSFTXVERY-UHFFFAOYSA-N

assay

95%

form

liquid

contains

copper as stabilizer

refractive index

n20/D 1.491 (lit.)

bp

99-100 °C (lit.)

mp

−38 °C (lit.)

density

1.544 g/mL at 25 °C (lit.)

functional group

alkyl halide
iodo

Quality Level

100

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General description

2-Iodo-2-methylpropane was degraded by reductive dehalogenation with nickel-aluminum alloy in potassium hydroxide solution.

signalword

Danger

Hazard Classifications

Acute Tox. 4 Oral - Aquatic Acute 1 - Eye Irrit. 2 - Flam. Liq. 2 - Skin Irrit. 2

Storage Class

3 - Flammable liquids

wgk

WGK 3

ppe

Eyeshields, Faceshields, Gloves, type ABEK (EN14387) respirator filter

Regulatory Information

危险化学品
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Certificates of Analysis (COA)

Lot/Batch Number
MKCX2813
MKCV6729
MKCT4560
MKCQ6315
MKCN4603

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Michael H Abraham et al.
Physical chemistry chemical physics : PCCP, 23(5), 3311-3320 (2021-02-03)
We have obtained properties (or descriptors) of the transition states in the solvolysis of tert-butyl chloride, bromide and iodide. We show that all three transition states, in both protic and in aprotic solvents, are highly dipolar and are strong hydrogen
Viktor P Bogdanov et al.
Chemistry, an Asian journal, 15(11), 1701-1708 (2020-04-16)
Alkylation of homofullerene [6,6]-C60 (CF2 )2- dianion with the set of alkyl halides, RX, was established to demonstrate an effect of RX nature on the conversion, product composition, and regioselectivity. The respective C60 (CF2 )RH, C60 (CF2 )R2 and C60
G Lunn et al.
American Industrial Hygiene Association journal, 52(6), 252-257 (1991-06-01)
Two techniques were investigated for degrading a number of halogenated compounds of commercial and research importance. Reductive dehalogenation with nickel-aluminum alloy in potassium hydroxide solution was used to degrade iodomethane, chloroacetic acid, trichloroacetic acid, 2-chloroethanol, 2-bromoethanol, 2-chloroethylamine, 2-bromoethylamine, 1-bromobutane, 1-iodobutane

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