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Merck
CN

24616

Vinyl chloroacetate

≥99.0%

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About This Item

Linear Formula:
ClCH2COOCH=CH2
CAS Number:
Molecular Weight:
120.53
UNSPSC Code:
12352100
NACRES:
NA.22
PubChem Substance ID:
EC Number:
219-834-3
Beilstein/REAXYS Number:
1745172
MDL number:
Assay:
≥99.0%
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Product Name

Vinyl chloroacetate, ≥99.0%

InChI key

XJELOQYISYPGDX-UHFFFAOYSA-N

InChI

1S/C4H5ClO2/c1-2-7-4(6)3-5/h2H,1,3H2

SMILES string

ClCC(=O)OC=C

assay

≥99.0%

contains

~0.01% hydroquinone monomethyl ether as stabilizer

refractive index

n20/D 1.444

density

1.192 g/mL at 20 °C

functional group

chloro
ester

storage temp.

2-8°C

Quality Level

Application

Vinyl chloroacetate was used to study the effect of the electron-withdrawing groups on the ligand in a series of bis(acetylacetonate)cobalt(II) derivatives.

Other Notes

Used for the enzyme-catalyzed, regioselective acylation of carbohydrates

pictograms

CorrosionExclamation mark

signalword

Danger

hcodes

Hazard Classifications

Acute Tox. 4 Oral - Eye Dam. 1 - Skin Corr. 1B

Storage Class

3 - Flammable liquids

wgk

WGK 3

flash_point_f

Not applicable

flash_point_c

Not applicable

ppe

Faceshields, Gloves, Goggles, type ABEK (EN14387) respirator filter

Regulatory Information

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E.W. Holla
Angewandte Chemie (International Edition in English), 101, 222-222 (1989)
Radical (co) polymerization of vinyl chloroacetate and N-vinylpyrrolidone mediated by bis (acetylacetonate) cobalt derivatives.
Kaneyoshi H and Matyjaszewski K.
Macromolecules, 39(8), 2757-2763 (2006)
Jérémie Brand et al.
Carbohydrate polymers, 169, 189-197 (2017-05-16)
Herein we propose a versatile method for the surface tailoring of cellulose nanocrystals (CNCs) based on the reactivity of vinyl ester molecules toward the accessible hydroxyl groups located at the surface of the nanoparticles. CNCs produced from wood pulp were

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