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Sigma-Aldrich

Vinyl chloroacetate

≥99.0%

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Linear Formula:
ClCH2COOCH=CH2
CAS Number:
2549-51-1
Molecular Weight:
120.53
Beilstein:
1745172
EC Number:
219-834-3
MDL number:
MFCD00045275
PubChem Substance ID:
57648091
NACRES:
NA.22

Quality Level

100

Assay

≥99.0%

contains

~0.01% hydroquinone monomethyl ether as stabilizer

refractive index

n20/D 1.444

density

1.192 g/mL at 20 °C

storage temp.

2-8°C

SMILES string

ClCC(=O)OC=C

InChI

1S/C4H5ClO2/c1-2-7-4(6)3-5/h2H,1,3H2

InChI key

XJELOQYISYPGDX-UHFFFAOYSA-N

Related Categories

Application

Vinyl chloroacetate was used to study the effect of the electron-withdrawing groups on the ligand in a series of bis(acetylacetonate)cobalt(II) derivatives.

Other Notes

Used for the enzyme-catalyzed, regioselective acylation of carbohydrates

Pictograms

CorrosionExclamation mark
GHS05,GHS07

Signal Word

Danger

Hazard Statements

H302 - H314

Hazard Classifications

Acute Tox. 4 Oral - Eye Dam. 1 - Skin Corr. 1B

Storage Class Code

3 - Flammable liquids

WGK

WGK 3

Flash Point(F)

Not applicable

Flash Point(C)

Not applicable

Personal Protective Equipment

dust mask type N95 (US), Eyeshields, Gloves

Regulatory Information

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Radical (co) polymerization of vinyl chloroacetate and N-vinylpyrrolidone mediated by bis (acetylacetonate) cobalt derivatives.
Kaneyoshi H and Matyjaszewski K.
Macromolecules, 39(8), 2757-2763 (2006)
E.W. Holla
Angewandte Chemie (International Edition in English), 101, 222-222 (1989)
Jérémie Brand et al.
Carbohydrate polymers, 169, 189-197 (2017-05-16)
Herein we propose a versatile method for the surface tailoring of cellulose nanocrystals (CNCs) based on the reactivity of vinyl ester molecules toward the accessible hydroxyl groups located at the surface of the nanoparticles. CNCs produced from wood pulp were

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