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Merck
CN

246174

Trimethoxymethylsilane

98%

Synonym(s):

Methyltrimethoxysilane

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About This Item

Linear Formula:
CH3Si(OCH3)3
CAS Number:
Molecular Weight:
136.22
UNSPSC Code:
12352103
NACRES:
NA.06
PubChem Substance ID:
EC Number:
214-685-0
Beilstein/REAXYS Number:
1736151
MDL number:
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Product Name

Trimethoxymethylsilane, 98%

InChI key

BFXIKLCIZHOAAZ-UHFFFAOYSA-N

InChI

1S/C4H12O3Si/c1-5-8(4,6-2)7-3/h1-4H3

SMILES string

CO[Si](C)(OC)OC

assay

98%

form

liquid

refractive index

n20/D 1.371 (lit.)

bp

102-104 °C (lit.)

density

0.955 g/mL at 25 °C (lit.)

Quality Level

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Application

Trimethoxymethylsilane can be used:
  • As a silica source for synthesizing polyethyleneimine-silica (PEI-silica) organic-inorganic hybrid particles.
  • To transform hydrophilic ceramic surfaces to hydrophobic by modifying the -OH groups.
  • To modify silica aerogels by inducing hydrophobicity and enhancing mechanical properties without affecting transparency.

General description

Trimethoxymethylsilane (MTM) is an organosilicon compound widely used as a precursor for the preparation of silica-based materials, which finds the applications in various fields. Particularly in molecular assembly, linking nano building blocks, and selective synthesis oligosiloxane compounds. It can also be utilized as a crosslinker in the synthesis of polysiloxane polymers.

pictograms

Flame

signalword

Danger

hcodes

Hazard Classifications

Flam. Liq. 2

Storage Class

3 - Flammable liquids

wgk

WGK 3

flash_point_f

48.2 °F

flash_point_c

9 °C

ppe

Eyeshields, Faceshields, Gloves, type ABEK (EN14387) respirator filter

Regulatory Information

危险化学品
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Utilization of alkoxysilyl groups for the creation of structurally controlled siloxane-based nanomaterials
Kuroda K, et al.
Chemistry of Materials, 26(1), 211-220 (2014)
The formation of polyethyleneimine?trimethoxymethylsilane organic?inorganic hybrid particles.
Neville F, et al.
Colloids and Surfaces. A, Physicochemical and Engineering Aspects, 431, 42-50 (2013)
Casseday P Richers et al.
Inorganic chemistry, 55(12), 5744-5746 (2016-06-04)
The commercially practiced conversion of trimethoxymethylsilane (MTM) to [OSi(OMe)Me)]n polymers and resins is assumed to proceed via the silanol (MeO)2MeSiOH. Access to this crucial silanol is gained via the synthesis of (MeO)2MeSiONa, the first methoxysilanoate to be crystallographically characterized. Mild
Investigation of Silane Modified Ceramic Surface of Porous Mullite Ceramics.
Markovska I, et al.
World Academy of Science, Engineering and Technology, 79(7), 272-276 (2013)
Organo-modified silica aerogels and implications for material hydrophobicity and mechanical properties.
Martin L, et al.
Journal of Materials Chemistry, 18(2), 207-213 (2008)

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