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Merck
CN

247650

Hexarhodium(0) hexadecacarbonyl

Rh 57-60 % (approx.)

Sustainability features

Synonym(s):

Rhodium(0) carbonyl

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About This Item

Linear Formula:
Rh6(CO)16
CAS Number:
Molecular Weight:
1065.59
NACRES:
NA.22
PubChem Substance ID:
UNSPSC Code:
12161600
EC Number:
249-009-3
MDL number:
Technical Service
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composition

Rh, 57-60% (approx.)

Quality Segment

reaction suitability

core: rhodium, reagent type: inorganic catalyst

sustainability

Sustainability features

greener alternative category

SMILES string

[Rh].[Rh].[Rh].[Rh].[Rh].[Rh].[C-]#[O+].[C-]#[O+].[C-]#[O+].[C-]#[O+].[C-]#[O+].[C-]#[O+].[C-]#[O+].[C-]#[O+].[C-]#[O+].[C-]#[O+].[C-]#[O+].[C-]#[O+].[C-]#[O+].[C-]#[O+].[C-]#[O+].[C-]#[O+]

InChI

1S/16CO.6Rh/c16*1-2;;;;;;

InChI key

SZQABOJVTZVBHE-UHFFFAOYSA-N

General description

We are committed to bringing you Greener Alternative Products, which adhere to one or more of the 12 Principles of Green Chemistry. This versatile precursor generates active rhodium carbonyl species for hydroformylation, carbonylative coupling, and reductive carbonylation. Its in situ generation enables cooperative multi-metal catalysis for complex transformations. Click here for more information.

Application

Widely used organometallic catalyst. Applications include the hydroformylation of olefins.
Catalyst for hydrogenation of alkenes, hydroformylations ofalkenes; reducing agent for aldehydes, ketones, and nitro groups; catalyst for carbenoid reactions of diazo compounds


Pictograms

Exclamation mark

Signal Word

Warning

Hazard Codes

Hazard Classifications

Acute Tox. 4 Dermal - Acute Tox. 4 Inhalation - Acute Tox. 4 Oral

Storage Class

11 - Combustible Solids

WGK

WGK 3

Flash Point (°F)

Not applicable

Flash Point (°C)

Not applicable

PPE (personal protective equipment)

dust mask type N95 (US), Eyeshields, Gloves



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