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248533

5-Norbornene-2-methanol

Name: 5-Norbornene-2-methanol
Brand: ALDRICH

98%, mixture of endo and exo

Synonym(s):

2-(Hydroxymethyl)bicyclo[2.2.1]hept-5-ene, 2-Hydroxymethyl-5-norbornene, 2-Norbornen-5-methanol, 5-(Hydroxymethyl)bicyclo[2.2.1]hept-2-ene, 5-Hydroxymethyl-2-norbornene, Bicyclo[2.2.1]hept-5-en-2-ylmethanol, Norbornene-5-methyl alcohol, [Bicyclo[2.2.1]hept-5-en-2-yl]methanol

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About This Item

Empirical Formula (Hill Notation):

C₈H₁₂O

CAS Number:

95-12-5

Molecular Weight:

124.18

NACRES:

NA.22

PubChem Substance ID:

24854934

UNSPSC Code:

12352100

EC Number:

202-392-0

MDL number:

MFCD00167571

Assay:

98%

Form:

liquid

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Properties

Quality Level

100

assay

98%

form

liquid

refractive index

n20/D 1.500 (lit.)

bp

97 °C/20 mmHg (lit.)

density

1.027 g/mL at 25 °C (lit.)

functional group

hydroxyl

SMILES string

OCC1C[C@@H]2C[C@H]1C=C2

InChI

1S/C8H12O/c9-5-8-4-6-1-2-7(8)3-6/h1-2,6-9H,3-5H2/t6-,7+,8?/m0/s1

InChI key

LUMNWCHHXDUKFI-KJFJCRTCSA-N

Description

General description

Co-polymerization of 5-norbornene-2-methanol with ethylene using heterogeneous silica supported catalysts has been reported.

Application

5-Norbornene-2-methanol has been used in the preparation of:

4-(norborn-2-ene-5-ylmethyleneoxy)-2,2′:6′,2′′-terpyridine
5- {[(3,5-di-t-butyl-4-hydroxy-benzoyl)oxy]methyl}-2-norbornene (BHBN)

pictograms

GHS07

signalword

Warning

hcodes

H302 + H312 + H332

pcodes

P261 - P264 - P280 - P301 + P312 - P302 + P352 + P312 - P304 + P340 + P312

Hazard Classifications

Acute Tox. 4 Oral

Storage Class

10 - Combustible liquids

wgk

WGK 3

flash_point_f

188.6 °F - closed cup

flash_point_c

87 °C - closed cup

ppe

Eyeshields, Faceshields, Gloves, type ABEK (EN14387) respirator filter

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Injectable Click Polypeptide Hydrogels via Tetrazine-Norbornene Chemistry for Localized Cisplatin Release.

Zhen Zhang et al.

Polymers, 12(4) (2020-04-16)

Injectable, covalently cross-linked hydrogels have been widely investigated in drug delivery systems due to their superior mechanical properties and long-term stability. Conventional covalently cross-linked hydrogels are formed by chemical reactions that may interfere with natural biochemical processes. In this work

Homogeneous and heterogeneous metallocene/MAO-catalyzed polymerization of functionalized olefins.

Goretzki R and Fink G.

Macromolecular Chemistry and Physics, 200(4), 881-886 (1999)

Access to heterogeneous atom-transfer radical polymerization (ATRP) catalysts based on dipyridylamine and terpyridine via ring-opening metathesis polymerization (ROMP).

Kroll R, et al.

Macromolecular Chemistry and Physics, 202(5), 645-653 (2001)

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Global Trade Item Number

SKU	GTIN
248533-5G	04061837331602