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About This Item
Linear Formula:
SOBr2
CAS Number:
Molecular Weight:
207.87
EC Number:
MDL number:
UNSPSC Code:
12352101
PubChem Substance ID:
NACRES:
NA.22
vapor pressure
10 mmHg ( 31 °C)
Quality Level
Assay
97%
form
liquid
refractive index
n20/D 1.675 (lit.)
bp
48 °C/20 mmHg (lit.)
mp
−52 °C (lit.)
density
2.683 g/mL at 25 °C (lit.)
storage temp.
2-8°C
SMILES string
BrS(Br)=O
InChI
1S/Br2OS/c1-4(2)3
InChI key
HFRXJVQOXRXOPP-UHFFFAOYSA-N
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Application
Thionyl bromide (SOBr2) can be used as a brominating agent in organic synthesis for the bromination of alcohols, carboxylic acids, alkenes, and ketones.
SoBr2 can be used in the synthesis of:
SoBr2 can be used in the synthesis of:
- ortho
- -Bromoanilides by bromination of ortho C-H bonds of the aryhydroxylamines.
- β-Amino bromides from β-aminoalcohols in the presence of DMF as a solvent.
- 4,8-Dibromobenzo[1,2-c;4,5-c′]bis[1,2,5]thiadiazole from 1,2,4,5-tetraaminobenzene tetrahydrobromide.
Signal Word
Danger
Hazard Statements
Precautionary Statements
Hazard Classifications
Acute Tox. 4 Dermal - Skin Corr. 1B
Supplementary Hazards
Storage Class Code
8A - Combustible corrosive hazardous materials
WGK
WGK 3
Flash Point(F)
Not applicable
Flash Point(C)
Not applicable
Personal Protective Equipment
dust mask type N95 (US), Eyeshields, Gloves
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