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Merck
CN

25170

1-(Chloromethyl)naphthalene

technical, ≥97.0% (GC)

Synonym(s):

1-Naphthylmethyl chloride

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About This Item

Linear Formula:
C10H7CH2Cl
CAS Number:
86-52-2
Molecular Weight:
176.64
EC Number:
201-678-2
UNSPSC Code:
12352100
NACRES:
NA.22
PubChem Substance ID:
57648117
Beilstein/REAXYS Number:
636885
MDL number:
MFCD00004042
Assay:
≥97.0% (GC)
Form:
solid

Key Documents

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Product Name

1-(Chloromethyl)naphthalene, technical, ≥97.0% (GC)

InChI key

XMWGTKZEDLCVIG-UHFFFAOYSA-N

InChI

1S/C11H9Cl/c12-8-10-6-3-5-9-4-1-2-7-11(9)10/h1-7H,8H2

SMILES string

ClCc1cccc2ccccc12

grade

technical

assay

≥97.0% (GC)

form

solid

color

deep brown

refractive index

n20/D 1.635 (lit.)
n20/D 1.635

bp

167-169 °C/25 mmHg (lit.)

mp

32 °C (lit.)

density

1.18 g/mL at 25 °C (lit.)

functional group

chloro

Quality Level

100

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General description

Kinetics and dissociation mechanism of 1-(chloromethyl)naphthalene following 266nm photoexcitation has been studied. Intermolecular nucleophilic dearomatization of 1-chloromethyl naphthalene with various activated methylene compounds has been investigated.

pictograms

CorrosionExclamation mark
GHS05,GHS07

signalword

Danger

Hazard Classifications

Acute Tox. 4 Dermal - Acute Tox. 4 Oral - Eye Dam. 1 - Skin Corr. 1B

Storage Class

8A - Combustible corrosive hazardous materials

wgk

WGK 3

flash_point_f

269.6 °F - closed cup

flash_point_c

132 °C - closed cup

ppe

Eyeshields, Faceshields, Gloves, type P3 (EN 143) respirator cartridges

Regulatory Information

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Certificates of Analysis (COA)

Lot/Batch Number
STBL4964
STBJ1328
STBH9997
STBD1932V
06209JJV

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Bo Peng et al.
Organic letters, 13(19), 5402-5405 (2011-09-14)
Palladium-catalyzed nucleophilic dearomatization of chloromethyl naphthalene derivatives to produce ortho- or para-substituted carbocycles in satisfactory to excellent yields has been developed. The unprecedented dearomatization reactions proceeded smoothly under mild conditions via η(3)-benzylpalladium intermediates.
Formation kinetics and spectra of aromatic radicals in solution.
Kelley DF, et al.
The Journal of Physical Chemistry, 87(11), 1842-1843 (1983)

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