252255
2-Chlorobenzyl bromide
97%
Synonym(s):
α-Bromo-2-chlorotoluene
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About This Item
Linear Formula:
ClC6H4CH2Br
CAS Number:
Molecular Weight:
205.48
UNSPSC Code:
12352100
NACRES:
NA.22
PubChem Substance ID:
EC Number:
210-257-2
Beilstein/REAXYS Number:
386264
MDL number:
Assay:
97%
Form:
liquid
InChI key
PURSZYWBIQIANP-UHFFFAOYSA-N
InChI
1S/C7H6BrCl/c8-5-6-3-1-2-4-7(6)9/h1-4H,5H2
SMILES string
Clc1ccccc1CBr
assay
97%
form
liquid
refractive index
n20/D 1.592 (lit.)
bp
103-104 °C/10 mmHg (lit.)
density
1.583 g/mL at 25 °C (lit.)
functional group
bromo, chloro
Quality Level
Related Categories
General description
2-Chlorobenzyl bromide participates in Hass-Bender oxidation as well as the Henry reaction.
signalword
Danger
hcodes
Hazard Classifications
Eye Dam. 1 - Skin Corr. 1B - STOT SE 3
target_organs
Respiratory system
Storage Class
8A - Combustible corrosive hazardous materials
wgk
WGK 3
flash_point_f
228.2 °F - closed cup
flash_point_c
109 °C - closed cup
ppe
Faceshields, Gloves, Goggles, type ABEK (EN14387) respirator filter
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Tandem Hass-Bender/Henry reaction for the synthesis of dimethylnitro alcohols from benzylic halides.
Klein TA and Schkeryantz JM.
Tetrahedron Letters, 46(27), 4535-4538 (2005)
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