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252255

2-Chlorobenzyl bromide

Name: 2-Chlorobenzyl bromide
Brand: ALDRICH

97%

Synonym(s):

α-Bromo-2-chlorotoluene

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About This Item

Linear Formula:

ClC₆H₄CH₂Br

CAS Number:

611-17-6

Molecular Weight:

205.48

UNSPSC Code:

12352100

NACRES:

NA.22

PubChem Substance ID:

24855194

EC Number:

210-257-2

Beilstein/REAXYS Number:

386264

MDL number:

MFCD00000566

Assay:

97%

Form:

liquid

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Properties

Quality Level

100

assay

97%

form

liquid

refractive index

n20/D 1.592 (lit.)

bp

103-104 °C/10 mmHg (lit.)

density

1.583 g/mL at 25 °C (lit.)

functional group

bromo, chloro

SMILES string

Clc1ccccc1CBr

InChI

1S/C7H6BrCl/c8-5-6-3-1-2-4-7(6)9/h1-4H,5H2

InChI key

PURSZYWBIQIANP-UHFFFAOYSA-N

Description

General description

2-Chlorobenzyl bromide participates in Hass-Bender oxidation as well as the Henry reaction.

pictograms

GHS05,GHS07

signalword

Danger

hcodes

H314,H335

pcodes

P261 - P271 - P280 - P303 + P361 + P353 - P304 + P340 + P310 - P305 + P351 + P338

Hazard Classifications

Eye Dam. 1 - Skin Corr. 1B - STOT SE 3

target_organs

Respiratory system

Storage Class

8A - Combustible corrosive hazardous materials

wgk

WGK 3

flash_point_f

228.2 °F - closed cup

flash_point_c

109 °C - closed cup

ppe

Faceshields, Gloves, Goggles, type ABEK (EN14387) respirator filter

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Tandem Hass-Bender/Henry reaction for the synthesis of dimethylnitro alcohols from benzylic halides.

Klein TA and Schkeryantz JM.

Tetrahedron Letters, 46(27), 4535-4538 (2005)

Global Trade Item Number

SKU	GTIN
252255-25G	04061837072000
252255-5G	04061825961712