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252867

2-(Benzyloxy)ethanol

Name: 2-(Benzyloxy)ethanol
Brand: ALDRICH

98%

Synonym(s):

Ethylene glycol monobenzyl ether

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About This Item

Linear Formula:

C₆H₅CH₂OCH₂CH₂OH

CAS Number:

622-08-2

Molecular Weight:

152.19

UNSPSC Code:

12352100

NACRES:

NA.22

PubChem Substance ID:

24855245

EC Number:

210-719-3

Beilstein/REAXYS Number:

2043566

MDL number:

MFCD00002868

Assay:

98%

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Properties

Quality Level

200

assay

98%

refractive index

n20/D 1.521 (lit.)

bp

265 °C (lit.)

density

1.071 g/mL at 25 °C (lit.)

functional group

ether, hydroxyl, phenyl

SMILES string

OCCOCc1ccccc1

InChI

1S/C9H12O2/c10-6-7-11-8-9-4-2-1-3-5-9/h1-5,10H,6-8H2

InChI key

CUZKCNWZBXLAJX-UHFFFAOYSA-N

Description

Application

2-(Benzyloxy)ethanol has been used in:

9-(2-hydroxyethyl)-linked synthesis of 2,6-diaminopurines
synthesis of benzyloxy ethyl methacrylate monomer by esterification with methacryloyl chloride
a base-free iridium-catalyzed direct alkylation of active methylene compounds with alcohols

pictograms

GHS07

signalword

Warning

hcodes

H302,H315,H319,H335

pcodes

P261 - P264 - P270 - P301 + P312 - P302 + P352 - P305 + P351 + P338

Hazard Classifications

Acute Tox. 4 Oral - Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3

target_organs

Respiratory system

Storage Class

10 - Combustible liquids

wgk

WGK 3

flash_point_f

230.0 °F - closed cup

flash_point_c

110 °C - closed cup

ppe

Eyeshields, Faceshields, Gloves, type ABEK (EN14387) respirator filter

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A structure-based library approach to kinase inhibitors.

Norman TC, et al.

Journal of the American Chemical Society, 118(31), 7430-7431 (1996)

Alkylation of active methylene compounds with alcohols catalyzed by an iridium complex.

Masao Morita et al.

Chemical communications (Cambridge, England), (27), 2850-2852 (2007-07-05)

Base-free catalytic alpha-alkylation of active methylene compounds with primary alcohols was successfully achieved using an [IrCl(cod)](2) complex in the presence of PPh(3) to afford the corresponding saturated alpha-alkylated products in good yields.

Poly (benzyloxy ethyl methacrylate): preparation by free radical polymerization and by group transfer polymerization; with subsequent debenzylation to form poly (2-hydroxyethyl methacrylate).

Dyakonov TA, et al.

Eur. Polymer J., 36(9), 1779-1793 (2000)

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Global Trade Item Number

SKU	GTIN
252867-5G	04061837633072
252867-25G	04061837633065