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Merck
CN

252913

5,10,15,20-Tetrakis(pentafluorophenyl)-21H,23H-porphyrin iron(III) chloride

≥95% (HPLC)

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About This Item

Empirical Formula (Hill Notation):
C44H8ClF20FeN4
CAS Number:
Molecular Weight:
1063.83
NACRES:
NA.23
PubChem Substance ID:
UNSPSC Code:
12352103
MDL number:
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Product Name

5,10,15,20-Tetrakis(pentafluorophenyl)-21H,23H-porphyrin iron(III) chloride, ≥95% (HPLC)

InChI

1S/C44H8F20N4.ClH.Fe/c45-25-21(26(46)34(54)41(61)33(25)53)17-9-1-2-10(65-9)18(22-27(47)35(55)42(62)36(56)28(22)48)12-5-6-14(67-12)20(24-31(51)39(59)44(64)40(60)32(24)52)16-8-7-15(68-16)19(13-4-3-11(17)66-13)23-29(49)37(57)43(63)38(58)30(23)50;;/h1-8H;1H;/q-2;;+3/p-1/b17-9+,17-11+,18-10+,18-12+,19-13+,19-15+,20-14+,20-16+;;

SMILES string

Fc1c(F)c(F)c(c(F)c1F)-c2c3ccc(n3)c(-c4c(F)c(F)c(F)c(F)c4F)c5ccc6c(-c7c(F)c(F)c(F)c(F)c7F)c8ccc(n8)c(-c9c(F)c(F)c(F)c(F)c9F)c%10ccc2n%10[Fe](Cl)n56

InChI key

RVNJZXLLVARDGN-VTVSBRCESA-M

assay

≥95% (HPLC)

form

powder

reaction suitability

reagent type: catalyst
core: iron

λmax

415 nm
498 nm (2nd)

Quality Level

Application

Catalyst for epoxidations with peroxides, oxidative decarbonylations, and aliphatic hydroxylations.

Features and Benefits

Catalyst for epoxidations with peroxides, oxidative decarbonylations, and aliphatic hydroxylations.
Preferred catalyst in catalytic oxygenation reactions.

pictograms

Exclamation mark

signalword

Warning

Hazard Classifications

Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3

target_organs

Respiratory system

Storage Class

11 - Combustible Solids

wgk

WGK 3

ppe

dust mask type N95 (US), Eyeshields, Gloves


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Tetrahedron Letters, 33, 4949-4949 (1992)
Journal of the American Chemical Society, 114, 1308-1308 (1992)
Journal of the American Chemical Society, 115, 2775-2775 (1993)

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