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255106

Dibromoborane dimethyl sulfide complex

Synonym(s):

Boron dibromide methyl sulfide complex, Dibromo(dimethyl sulfide)(hydro)boron, Dibromo(dimethyl sulfide)borane, Dibromoborane compound with dimethylsulfane, Dibromoborane dimethyl sulfide

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About This Item

Linear Formula:
(CH3)2S · BHBr2
CAS Number:
55671-55-1
Molecular Weight:
233.76
UNSPSC Code:
12352112
NACRES:
NA.22
PubChem Substance ID:
24855287
MDL number:
MFCD00011601
Beilstein/REAXYS Number:
4449985
Form:
solid
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form

solid

Quality Level

100

reaction suitability

reagent type: reductant

mp

30-35 °C (lit.)

functional group

thioether

SMILES string

CSC.BrBBr

InChI

1S/C2H6S.BBr2H/c1-3-2;2-1-3/h1-2H3;1H

InChI key

PGSRDLGPKTVELT-UHFFFAOYSA-N

Application

Reactant for:
  • Reductive elimination C-C bond forming reactions
  • Lithiation-borylation reaction with Hoppe′s lithiated carbamates
  • Preparation of boron analogues of uracil
  • Boronation reactions for formation of cyclic boronium salts
  • Hydroboration reactions
  • Ring opening of terminal epoxides

pictograms

FlameCorrosion
GHS02,GHS05

signalword

Danger

supp_hazards

EUH014

Storage Class

4.3 - Hazardous materials which set free flammable gases upon contact with water

wgk

WGK 3

flash_point_f

78.8 °F - closed cup

flash_point_c

26 °C - closed cup

ppe

Eyeshields, Faceshields, Gloves, type P3 (EN 143) respirator cartridges

Hazard Classifications

Flam. Sol. 1 - Skin Corr. 1B - Water-react. 2

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Certificates of Analysis (COA)

Lot/Batch Number
SHBM1172
SHBR3569
SHBF8891V
SHBF1699V
SHBF1473V

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Global Trade Item Number

SKUGTIN
255106-100G04061833490075