255106
二溴硼烷甲硫醚络合物
别名:
二溴甲基硫醚化硼络合物
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线性分子式:
(CH3)2S · BHBr2
化学文摘社编号:
分子量:
233.76
UNSPSC Code:
12352112
NACRES:
NA.22
PubChem Substance ID:
MDL number:
Beilstein/REAXYS Number:
4449985
Form:
solid
InChI
1S/C2H6S.BBr2H/c1-3-2;2-1-3/h1-2H3;1H
SMILES string
CSC.BrBBr
InChI key
PGSRDLGPKTVELT-UHFFFAOYSA-N
form
solid
reaction suitability
reagent type: reductant
mp
30-35 °C (lit.)
functional group
thioether
Quality Level
Application
Reactant for:
- Reductive elimination C-C bond forming reactions
- Lithiation-borylation reaction with Hoppe′s lithiated carbamates
- Preparation of boron analogues of uracil
- Boronation reactions for formation of cyclic boronium salts
- Hydroboration reactions
- Ring opening of terminal epoxides
signalword
Danger
hcodes
Hazard Classifications
Flam. Sol. 1 - Skin Corr. 1B - Water-react 2
supp_hazards
存储类别
4.3 - Hazardous materials which set free flammable gases upon contact with water
wgk
WGK 3
flash_point_f
78.8 °F - closed cup
flash_point_c
26 °C - closed cup
ppe
Eyeshields, Faceshields, Gloves, type P3 (EN 143) respirator cartridges
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