257044
L-Selectride® solution
1.0 M lithium tri-sec-butylborohydride in THF
Synonym(s):
Lithium tri-sec-butylborohydride solution
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About This Item
InChI
1S/C12H28B.Li/c1-7-10(4)13(11(5)8-2)12(6)9-3;/h10-13H,7-9H2,1-6H3;/q-1;+1
SMILES string
[Li+].[H][B-](C(C)CC)(C(C)CC)C(C)CC
InChI key
ACJKNTZKEFMEAK-UHFFFAOYSA-N
form
liquid
reaction suitability
reagent type: reductant
concentration
1.0 M lithium tri-sec-butylborohydride in THF
density
0.89 g/mL at 25 °C
Quality Level
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Application
- Reducing agent
Reagent for:
- Enantioselective synthesis of a-amino acids via reduction of N-tert-butanesulfinyl ketimine esters
- Diastereoselective reduction reactions
- Hydride reduction of the Danishefsky pyranones
- Asymmetric reductive aldol reaction of enones with a-alkoxy aldehydes
- Synthesis of alkanols by carbonylation reactions
Packaging
Compatible with the following:
- Aldrich® Sure/Pac™ station for liquefied gases Z566446
- PTFE Sealing tape Z104388 or Z221880
- Straight septum-inlet adapter Z118141 with septa Z565687 or Z565695
Legal Information
signalword
Danger
Hazard Classifications
Carc. 2 - Flam. Liq. 2 - Pyr. Liq. 1 - Skin Corr. 1B - STOT SE 3 - Water-react 1
target_organs
Respiratory system
supp_hazards
Storage Class
4.2 - Pyrophoric and self-heating hazardous materials
wgk
WGK 3
flash_point_f
1.4 °F - closed cup
flash_point_c
-17 °C - closed cup
ppe
Faceshields, Gloves, Goggles, type ABEK (EN14387) respirator filter
Regulatory Information
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