257044
L-Selectride® 溶液
1.0 M lithium tri-sec-butylborohydride in THF
别名:
三仲丁基硼氢化锂 溶液
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关于此项目
线性分子式:
Li[CH(CH3)CH2CH3]3BH
化学文摘社编号:
分子量:
190.10
UNSPSC Code:
12352000
NACRES:
NA.22
PubChem Substance ID:
MDL number:
Beilstein/REAXYS Number:
4007327
Form:
liquid
InChI
1S/C12H28B.Li/c1-7-10(4)13(11(5)8-2)12(6)9-3;/h10-13H,7-9H2,1-6H3;/q-1;+1
SMILES string
[Li+].[H][B-](C(C)CC)(C(C)CC)C(C)CC
InChI key
ACJKNTZKEFMEAK-UHFFFAOYSA-N
form
liquid
reaction suitability
reagent type: reductant
concentration
1.0 M lithium tri-sec-butylborohydride in THF
density
0.89 g/mL at 25 °C
Quality Level
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Application
- 还原剂
用作以下反应的试剂：
- 通过还原N-叔丁基亚磺酰基酮亚胺酯，实现α-氨基酸的对映选择性合成
- 非对映选择性还原反应
- Danishefsky吡喃酮的氢化还原
- 烯酮与α-烷氧基醛的不对称还原性醛醇反应
- 通过羰基化反应合成链烷醇
Packaging
Supplied in a Sure/Pac™ cylinder and has a 1/4-turn bronze ball valve with a female 1/4" NPT outlet thread (Z122661) installed. Before using the cylinder, ensure that the valve is closed, then remove carbon steel plug that seals the outlet valve.
Compatible with the following:
Compatible with the following:
- Aldrich® Sure/Pac™ station for liquefied gases Z566446
- PTFE Sealing tape Z104388 or Z221880
- Straight septum-inlet adapter Z118141 with septa Z565687 or Z565695
Legal Information
Aldrich is a registered trademark of Sigma-Aldrich Co. LLC
Selectride is a registered trademark of Merck KGaA, Darmstadt, Germany
Sure/Pac is a trademark of Sigma-Aldrich Co. LLC
signalword
Danger
Hazard Classifications
Carc. 2 - Flam. Liq. 2 - Pyr. Liq. 1 - Skin Corr. 1B - STOT SE 3 - Water-react 1
target_organs
Respiratory system
supp_hazards
存储类别
4.2 - Pyrophoric and self-heating hazardous materials
wgk
WGK 3
flash_point_f
1.4 °F - closed cup
flash_point_c
-17 °C - closed cup
ppe
Faceshields, Gloves, Goggles, type ABEK (EN14387) respirator filter
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