257214
Triisobutylaluminum solution
25 wt. % in toluene
Synonym(s):
TIBA solution
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About This Item
Linear Formula:
[(CH3)2CHCH2]3Al
CAS Number:
Molecular Weight:
198.32
PubChem Substance ID:
UNSPSC Code:
12352103
Beilstein/REAXYS Number:
3587328
MDL number:
form
liquid
Quality Level
concentration
25 wt. % in toluene
density
0.848 g/mL at 25 °C
SMILES string
CC(C)C[Al](CC(C)C)CC(C)C
InChI
1S/3C4H9.Al/c3*1-4(2)3;/h3*4H,1H2,2-3H3;
InChI key
MCULRUJILOGHCJ-UHFFFAOYSA-N
Packaging
Supplied in a Sure/Pac™ cylinder and has a 1/4-turn bronze ball valve with a female 1/4" NPT outlet thread (Z122661) installed. Before using the cylinder, ensure that the valve is closed, then remove carbon steel plug that seals the outlet valve.
Compatible with the following:
Compatible with the following:
- Aldrich® Sure/Pac™ station for liquefied gases Z566446
- PTFE Sealing tape Z104388 or Z221880
- Straight septum-inlet adapter Z118141 with septa Z565687 or Z565695
Legal Information
Aldrich is a registered trademark of Sigma-Aldrich Co. LLC
Sure/Pac is a trademark of Sigma-Aldrich Co. LLC
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Danger
Hazard Classifications
Aquatic Chronic 3 - Asp. Tox. 1 - Eye Dam. 1 - Flam. Liq. 2 - Pyr. Liq. 1 - Repr. 2 - Skin Corr. 1B - STOT RE 2 - STOT SE 3 - Water-react. 1
target_organs
Central nervous system
Storage Class
4.2 - Pyrophoric and self-heating hazardous materials
wgk
WGK 3
flash_point_f
-0.4 °F - closed cup
flash_point_c
-18 °C - closed cup
Regulatory Information
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Nandita M Weliange et al.
Dalton transactions (Cambridge, England : 2003), 44(34), 15286-15296 (2015-06-05)
The insertion, elimination and isomerisation of octenes with di-n-octylaluminium hydride [HAl(Oct)2], tri-n-octylaluminium [Al(Oct)3] and sec-octylaluminium species have been studied as individual steps in a putative aluminium based contrathermodynamic olefin isomerisation process. While elimination of 1-octene from [Al(Oct)3] is energetically unfavourable
Yunhong Zhang et al.
Carbohydrate polymers, 113, 446-454 (2014-09-27)
Alginate oligosaccharides (AOS), which are marine oligosaccharides, are involved in regulating plant root growth, but the promotion mechanism for AOS remains unclear. Here, AOS (10-80 mg/L) induced the expression of auxin-related gene (OsYUCCA1, OsYUCCA5, OsIAA11 and OsPIN1) in rice (Oryza
Inmaculada Suárez et al.
Journal of chromatography. A, 1407, 193-202 (2015-07-15)
Average molecular weights and polydispersity indexes are some of the most important parameters considered in the polymer characterization. Usually, gel permeation chromatography (GPC) and multi angle light scattering (MALS) are used for this determination, but GPC values are overestimated due
Global Trade Item Number
| SKU | GTIN |
|---|---|
| 257214-100G | 04061826059203 |