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Merck
CN

257532

2,3,7,8,12,13,17,18-Octaethyl-21H,23H-porphine iron(III) chloride

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About This Item

Empirical Formula (Hill Notation):
C36H44ClFeN4
CAS Number:
28755-93-3
Molecular Weight:
624.06
NACRES:
NA.23
PubChem Substance ID:
24855420
UNSPSC Code:
12352103
MDL number:
MFCD00011614

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InChI

1S/C36H44N4.ClH.Fe/c1-9-21-22(10-2)30-18-32-25(13-5)26(14-6)34(39-32)20-36-28(16-8)27(15-7)35(40-36)19-33-24(12-4)23(11-3)31(38-33)17-29(21)37-30;;/h17-20H,9-16H2,1-8H3;1H;/q-2;;+3/p-1/b29-17-,30-18-,31-17-,32-18-,33-19-,34-20-,35-19-,36-20-;;

SMILES string

CCc1c(CC)c2cc3c(CC)c(CC)c4cc5nc(cc6c(CC)c(CC)c(cc1n2)n6[Fe](Cl)n34)c(CC)c5CC

InChI key

NWWCYXFDLUMYRQ-YAJYDHHFSA-M

form

solid

λmax

382 nm

Quality Level

100

Related Categories

General description

2,3,7,8,12,13,17,18-Octaethyl-21H,23H-porphine metalates with iron chloride to form 2,3,7,8,12,13,17,18-Octaethyl-21H,23H-porphine iron chloride (FeOEP). It may be used to form Langmuir Blodgett (LB) thin films. Iron–porphyrin could be present naturally in biofilms.

Application

An iron–porphyrin adlayer adsorbed on the Au(111) substrate was used to study the electrocatalytic reduction of O2 in HClO4.

Storage Class

11 - Combustible Solids

wgk

WGK 3

flash_point_f

Not applicable

flash_point_c

Not applicable

ppe

Eyeshields, Gloves, type N95 (US)

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Certificates of Analysis (COA)

Lot/Batch Number
MKCK8517
11102EH
21919BO
12116JQ
04006TW

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In Situ Scanning Tunneling Microscopy Study of the Effect of Iron Octaethylporphyrin Adlayer on the Electrocatalytic Reduction of O2 on Au (111)
Yoshimoto S, et al.
The Journal of Physical Chemistry B, 108(17), 5171-5174 (2044)

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