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257532

2,3,7,8,12,13,17,18-Octaethyl-21H,23H-porphine iron(III) chloride

Name: 2,3,7,8,12,13,17,18-Octaethyl-21<I>H</I>,23<I>H</I>-porphine iron(III) chloride
Brand: ALDRICH

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About This Item

Empirical Formula (Hill Notation):

C₃₆H₄₄ClFeN₄

CAS Number:

28755-93-3

Molecular Weight:

624.06

NACRES:

NA.23

PubChem Substance ID:

24855420

UNSPSC Code:

12352103

MDL number:

MFCD00011614

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Properties

form

solid

λ_max

382 nm

SMILES string

CCc1c(CC)c2cc3c(CC)c(CC)c4cc5nc(cc6c(CC)c(CC)c(cc1n2)n6[Fe](Cl)n34)c(CC)c5CC

InChI

1S/C36H44N4.ClH.Fe/c1-9-21-22(10-2)30-18-32-25(13-5)26(14-6)34(39-32)20-36-28(16-8)27(15-7)35(40-36)19-33-24(12-4)23(11-3)31(38-33)17-29(21)37-30;;/h17-20H,9-16H2,1-8H3;1H;/q-2;;+3/p-1/b29-17-,30-18-,31-17-,32-18-,33-19-,34-20-,35-19-,36-20-;;

InChI key

NWWCYXFDLUMYRQ-YAJYDHHFSA-M

Description

General description

2,3,7,8,12,13,17,18-Octaethyl-21H,23H-porphine metalates with iron chloride to form 2,3,7,8,12,13,17,18-Octaethyl-21H,23H-porphine iron chloride (FeOEP). It may be used to form Langmuir Blodgett (LB) thin films. Iron–porphyrin could be present naturally in biofilms.

Application

An iron–porphyrin adlayer adsorbed on the Au(111) substrate was used to study the electrocatalytic reduction of O₂ in HClO₄.

Storage Class

11 - Combustible Solids

WGK

WGK 3

Flash Point (°F)

Not applicable

Flash Point (°C)

Not applicable

PPE (personal protective equipment)

Eyeshields, Gloves, type N95 (US)

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