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Merck
CN

262005

Hexaammineruthenium(III) chloride

98%, powder

Synonym(s):

Hexaammineruthenium trichloride

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About This Item

Linear Formula:
[Ru(NH3)6]Cl3
CAS Number:
14282-91-8
Molecular Weight:
309.61
NACRES:
NA.22
PubChem Substance ID:
24855851
UNSPSC Code:
12161600
EC Number:
238-176-8
MDL number:
MFCD00011478

Key Documents

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Product Name

Hexaammineruthenium(III) chloride, 98%

InChI key

GBDZMMXUOBAJMN-UHFFFAOYSA-K

InChI

1S/3ClH.6H3N.Ru/h3*1H;6*1H3;/q;;;;;;;;;+3/p-3

SMILES string

N.N.N.N.N.N.[Cl-].[Cl-].[Cl-].[Ru+3]

assay

98%

form

powder

reaction suitability

core: ruthenium
reagent type: catalyst

storage temp.

2-8°C

Quality Level

100

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Application

Hexaammineruthenium(III) chloride can be used as a precursor for the preparation of:
  • Ru/Al2O3 catalyst for CO2 hydrogenation.
  • Bimetallic complexes ([Ru(NH3)6][Ag(CN)2]3·2H2O).
  • Chloropentaammineruthenium(III) chloride.
For small scale and high throughput uses, product is also available as ChemBeads (932183)

General description

Hexaammineruthenium III/II (HexRu(III)|HexRu(II)) couple is a commonly used electrochemical redox couple due to its chemical and electrochemical reversibility.

pictograms

Exclamation mark
GHS07

signalword

Warning

Hazard Classifications

Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3

target_organs

Respiratory system

Storage Class

13 - Non Combustible Solids

wgk

WGK 3

flash_point_f

Not applicable

flash_point_c

Not applicable

ppe

dust mask type N95 (US), Eyeshields, Gloves

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Certificates of Analysis (COA)

Lot/Batch Number
WXBF7533V
WXBF7534V
WXBF7535V
MKCZ7347
MKCZ0926

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Binuclear complexes of ruthenium ammines.
Creutz C and Taube H
Journal of the American Chemical Society, 95(4), 1086-1094 (1973)
CO2 Hydrogenation over Ru/chi-Al2O3 Catalyst
Jeenjumras K, et al.
IOP Conference Series: Materials Science and Engineering, 311, 012023-012023 (2018)
Qian Yang et al.
Nanoscale, 9(46), 18523-18528 (2017-11-23)
A molecular check valve is a nanomachine that enables unidirectional molecular transport. In this work, we report a novel molecular check valve fabricated by asymmetric modification of a silica nanoporous membrane (SNM) consisting of parallel nanochannels with a diameter of
Assisted self-association of dicyanoaurate,[Au (CN) 2]-, and dicyanoargentate,[Ag (CN) 2]-, through hydrogen bonding to metal ammonia complexes
Pham D, et al.
Inorganica chimica acta, 358, 4261-4269 (2005)
Juan Yao et al.
The Analyst, 142(21), 4116-4123 (2017-10-11)
An isothermal, enzyme free, ultra-specific and ultra-sensitive protocol for electrochemical detection of miRNAs is proposed based on the toehold-mediated strand displacement reaction (SDR) and non-enzymatic catalytic hairpin reaction (CHA) recycling. The SDR was first triggered only in the presence of
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