262099
Phosphorus(V) oxychloride
99.999%
Synonym(s):
Phosphorus(V) oxide chloride, Phosphoryl chloride
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About This Item
vapor density
5.3 (vs air)
Quality Segment
vapor pressure
104 mmHg ( 50 °C), 28 mmHg ( 20 °C)
assay
99.999%
form
liquid
reaction suitability
reaction type: Halogenations
pH
1 (20 °C)
bp
105.8 °C (lit.)
mp
1.25 °C (lit.)
density
1.645 g/mL at 25 °C (lit.)
functional group
phosphine oxide
SMILES string
ClP(Cl)(Cl)=O
InChI
1S/Cl3OP/c1-5(2,3)4
InChI key
XHXFXVLFKHQFAL-UHFFFAOYSA-N
Application
- A dehydrating agent in organic synthesis.
- A reagent in the cyclization of substituted aryl amides by Bischler−Napieralski cyclization reaction.
- A precursor for phosphorus diffusion in the p-type silicon solar cells processing.
It can also be used in the Vilsmeier-Haack reaction to synthesize aromatic aldehydes.
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Signal Word
Danger
Hazard Codes
Precautionary Statements
Hazard Classifications
Acute Tox. 2 Inhalation - Acute Tox. 4 Oral - Eye Dam. 1 - Skin Corr. 1A - STOT RE 1 Inhalation
Target Organs
Respiratory Tract
supp_hazards
Storage Class
6.1B - Non-combustible acute toxic Cat. 1 and 2 / very toxic hazardous materials
WGK
WGK 1
Flash Point (°F)
Not applicable
Flash Point (°C)
Not applicable
PPE (personal protective equipment)
Faceshields, Gloves, Goggles, type ABEK (EN14387) respirator filter
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