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271411

Allyltributylstannane

97%

Synonym(s):

Allyltri-n-butyltin, Allyltributyltin, Tributyl-2-propenylstannane

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About This Item

Linear Formula:
CH2=CHCH2Sn(CH2CH2CH2CH3)3
CAS Number:
24850-33-7
Molecular Weight:
331.12
UNSPSC Code:
12352103
NACRES:
NA.22
PubChem Substance ID:
24856436
EC Number:
246-494-3
Beilstein/REAXYS Number:
3588340
MDL number:
MFCD00010346
Assay:
97%
Form:
liquid
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Quality Level

100

assay

97%

form

liquid

refractive index

n20/D 1.486 (lit.)

bp

88-92 °C/0.2 mmHg (lit.)

density

1.068 g/mL at 25 °C (lit.)

SMILES string

CCCC[Sn](CCCC)(CCCC)CC=C

InChI

1S/3C4H9.C3H5.Sn/c3*1-3-4-2;1-3-2;/h3*1,3-4H2,2H3;3H,1-2H2;

InChI key

YLGRTLMDMVAFNI-UHFFFAOYSA-N

Application

Allylation reagent for aldehydes catalyzed by chiral Lewis acids and ytterbium(III) trifluoromethanesulfonate (cat. no. 430595). Undergoes tetrakis(triphenylphosphine)palladium(0) (cat. no. 216666) catalyzed coupling with iodoquinones and allyl acetates.
Efficient allylation of aldehydes leading to homoallylic alcohols with trichloro-1,3,5-triazene.

signalword

Danger

Hazard Classifications

Acute Tox. 3 Oral - Acute Tox. 4 Dermal - Aquatic Acute 1 - Aquatic Chronic 1 - Eye Irrit. 2 - Repr. 1B - Skin Irrit. 2 - STOT RE 1

Storage Class

6.1C - Combustible acute toxic Cat.3 / toxic compounds or compounds which causing chronic effects

wgk

WGK 3

flash_point_f

217.4 °F - closed cup

flash_point_c

103 °C - closed cup

ppe

Eyeshields, Faceshields, Gloves, type ABEK (EN14387) respirator filter

Regulatory Information

监管及禁止进口产品

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Certificates of Analysis (COA)

Lot/Batch Number
MKCX2801
MKCT7319
SHBL0295
SHBH7121
SHBF1483V

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Aldrichimica Acta, 20, 45-45 (1987)
Journal of the American Chemical Society, 115, 8467-8467 (1993)
Tetrahedron Letters, 34, 7827-7827 (1993)
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Global Trade Item Number

SKUGTIN
271411-100G04061838119001
271411-5G04061838090157
271411-25G04061826143773