274585
Methyl trimethylsilyl dimethylketene acetal
95%
Synonym(s):
1-Methoxy-2-methyl-1-(trimethylsiloxy)propene, (1-Methoxy-2-methyl-1-propenyloxy)trimethylsilane, MTDA
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About This Item
Product Name
Methyl trimethylsilyl dimethylketene acetal, 95%
Quality Level
InChI
1S/C8H18O2Si/c1-7(2)8(9-3)10-11(4,5)6/h1-6H3
SMILES string
CO\C(O[Si](C)(C)C)=C(/C)C
InChI key
JNOGVQJEBGEKMG-UHFFFAOYSA-N
assay
95%
form
liquid
refractive index
n20/D 1.415 (lit.)
bp
35 °C/15 mmHg (lit.)
density
0.858 g/mL at 25 °C (lit.)
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Application
- in the synthesis of chiral β-lactams by reacting with (S)-alkylidene(1-arylethyl)amines in the presence of titanium tetrachloride
- as a catalyst or initiator in the group-transfer polymerization
- as a versatile reagent in conjugate addition and aldol reactions.
signalword
Warning
hcodes
Hazard Classifications
Eye Irrit. 2 - Flam. Liq. 3 - Skin Irrit. 2 - STOT SE 3
target_organs
Respiratory system
Storage Class
3 - Flammable liquids
wgk
WGK 3
flash_point_f
86.0 °F - closed cup
flash_point_c
30 °C - closed cup
ppe
Eyeshields, Faceshields, Gloves, type ABEK (EN14387) respirator filter
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