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4-(Diethoxymethyl)benzaldehyde

Name: 4-(Diethoxymethyl)benzaldehyde
Brand: ALDRICH

97%

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Synonym(s):

Terephthalaldehyde diethyl acetal

Linear Formula:

(C₂H₅O)₂CHC₆H₄CHO

CAS Number:

81172-89-6

Molecular Weight:

208.25

Beilstein:

4293872

MDL number:

MFCD00010217

PubChem Substance ID:

24856610

NACRES:

NA.22

Quality Level

100

Assay

97%

form

liquid

refractive index

n20/D 1.506 (lit.)

density

1.047 g/mL at 25 °C (lit.)

SMILES string

[H]C(=O)c1ccc(cc1)C(OCC)OCC

InChI

1S/C12H16O3/c1-3-14-12(15-4-2)11-7-5-10(9-13)6-8-11/h5-9,12H,3-4H2,1-2H3

InChI key

HTMXMFARWHNJDW-UHFFFAOYSA-N

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Related Categories

Organic Building Blocks

Application

4-(Diethoxymethyl)benzaldehyde was used in the synthesis of 4-(diethoxymethyl)benzyl alcohol.

Storage Class Code

10 - Combustible liquids

WGK

WGK 3

Flash Point(F)

Not applicable

Flash Point(C)

Not applicable

Personal Protective Equipment

dust mask type N95 (US), Eyeshields, Gloves

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Synthesis of heterotelechelic poly(ethylene glycol) derivatives having alpha-benzaldehyde and omega-pyridyl disulfide groups by ring opening polymerization of ethylene oxide using 4-(diethoxymethyl)benzyl alkoxide as a novel initiator.

Yoshitsugu Akiyama et al.

Bioconjugate chemistry, 15(2), 424-427 (2004-03-18)

New heterotelechelic PEG-containing benzaldehyde and 2-pyridyldithio endgroup (CHO-Bz-PEG-SSpyl) was synthesized with high efficiency and high selectivity. An alpha-benzylacetal-omega-methansulfonyl PEG was prepared as the first step to CHO-Bz-PEG-SSpyl through the ring-opening polymerization of ethylene oxide (EO) initiated by potassium 4-(diethoxymethyl)benzyl alkoxide

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