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Merck
CN

275573

4-Hydroxybutyl acrylate

90%, contains 50 ppm monomethyl ether hydroquinone as inhibitor, 300 ppm hydroquinone as inhibitor

Synonym(s):

1,4-Butanediol acrylate, Tetramethylene glycol monoacrylate

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About This Item

Linear Formula:
H2C=CHCO2(CH2)4OH
CAS Number:
2478-10-6
Molecular Weight:
144.17
NACRES:
NA.23
PubChem Substance ID:
24856656
UNSPSC Code:
12162002
EC Number:
219-606-3
MDL number:
MFCD00010261

Key Documents

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Product Name

4-Hydroxybutyl acrylate, 90%, contains 50 ppm monomethyl ether hydroquinone as inhibitor, 300 ppm hydroquinone as inhibitor

InChI key

NDWUBGAGUCISDV-UHFFFAOYSA-N

InChI

1S/C7H12O3/c1-2-7(9)10-6-4-3-5-8/h2,8H,1,3-6H2

SMILES string

OCCCCOC(=O)C=C

assay

90%

contains

300 ppm hydroquinone as inhibitor
50 ppm monomethyl ether hydroquinone as inhibitor

refractive index

n20/D 1.452 (lit.)

bp

95 °C/0.1 mmHg (lit.)

density

1.041 g/mL at 25 °C (lit.)

storage temp.

2-8°C

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Application

Hydroxybutyl acrylate was one of the monomers utilized in the preparation of poly(2-hydroxy-3-phenoxypropylacrylate, 4-hydroxybutyl acrylate, dibutyl maleate) membranes.

General description

4-Hydroxybutyl acrylate (HBA) can be synthesized by the esterification of acrylic acid with 1, 4 butanediol over a catalyst such as Amberlyst 15. 4-Hydroxybutyl acrylate (HBA) exhibits properties such as luster, chemical and scratch resistance. HBA monomers may be used as one of the constituents for the fabrication of a membrane system for controlled release of transdermal drug delivery system.

signalword

Danger

pictograms

CorrosionExclamation mark
GHS05,GHS07

Hazard Classifications

Acute Tox. 4 Oral - Eye Dam. 1 - Skin Irrit. 2 - Skin Sens. 1

Storage Class

10 - Combustible liquids

wgk

WGK 1

flash_point_f

235.4 °F - closed cup

flash_point_c

113 °C - closed cup

ppe

Eyeshields, Faceshields, Gloves, type ABEK (EN14387) respirator filter

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Certificates of Analysis (COA)

Lot/Batch Number
05602JJ
05521HE
2509BL

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A new poly(2-hydroxy-3-phenoxypropylacrylate, 4-hydroxybutyl acrylate, diethyl maleate) membrane controlled clonidine linear release in the transdermal drug delivery system.
Zhan X, et al.
European Polymer Journal, 43(4), 1588-1594 (2007)
Agnieszka Kowalczyk et al.
Polymers, 11(12) (2019-12-15)
New organic-inorganic hybrid copolymers (EA-POSSs) based on butyl acrylate, glycidyl methacylate, hydroxybutyl acrylate, acryloiloxybenzophenone and acryloxypropyl-heptaisobutyl-POSS (A-POSS) were prepared via free-radical solution polymerization (FRP) and applied as a component of thermally curable structural self-adhesive tapes (SATs). The EA-POSS with 0.25
Production of 4?Hydroxybutyl Acrylate and Its Reaction Kinetics over Amberlyst 15 Catalyst.
Yang J, et al.
The Canadian Journal of Chemical Engineering, 85(1), 83-91 (2007)
Qian Zhao et al.
Journal of materials chemistry. B, 8(40), 9362-9373 (2020-10-01)
A series of novel nanofibrillated cellulose (NFC) reinforced gradient intelligent hydrogels with high response rate, multiple response patterns and diversified self-driven functions were successfully prepared. Based on the effect of the hydroxide radical of NFC on the addition reaction, and
A new poly(2-hydroxy-3-phenoxypropylacrylate, 4-hydroxybutyl acrylate, diethyl maleate) membrane controlled clonidine linear release in the transdermal drug delivery system.
Zhan X< et al.
European Polymer Journal, 43(4), 83-91 (2007)
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