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Merck
CN

277037

(1R,2R)-(+)-1-Phenylpropylene oxide

97%

Synonym(s):

(2R,3R)-(+)-2-Methyl-3-phenyloxirane

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About This Item

Empirical Formula (Hill Notation):
C9H10O
CAS Number:
14212-54-5
Molecular Weight:
134.18
NACRES:
NA.22
PubChem Substance ID:
24856729
UNSPSC Code:
12352005
MDL number:
MFCD00064482
Assay:
97%
Form:
liquid

Key Documents

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InChI

1S/C9H10O/c1-7-9(10-7)8-5-3-2-4-6-8/h2-7,9H,1H3/t7-,9+/m1/s1

SMILES string

C[C@H]1O[C@@H]1c2ccccc2

InChI key

YVCOJTATJWDGEU-APPZFPTMSA-N

assay

97%

form

liquid

optical activity

[α]20/D +110°, neat

optical purity

ee: 99% (GLC)

refractive index

n20/D 1.518 (lit.)

bp

201-207 °C (lit.)

density

1.006 g/mL at 25 °C (lit.)

Application

Chiral building block. Tool for studying enzyme hydrolysis rates.

pictograms

Exclamation mark
GHS07

signalword

Warning

Hazard Classifications

Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3

target_organs

Respiratory system

Storage Class

10 - Combustible liquids

wgk

WGK 3

flash_point_f

156.2 °F - closed cup

flash_point_c

69 °C - closed cup

ppe

Eyeshields, Gloves, type ABEK (EN14387) respirator filter

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Certificates of Analysis (COA)

Lot/Batch Number
53497LJV
53497LJ
08420MD
14226BF
12015JR

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B D Hammock et al.
Biochemical pharmacology, 32(7), 1155-1164 (1983-04-01)
The initial rates of hydration of sixteen epoxides in the presence of cytosolic and microsomal fractions of mouse liver were determined. 1,2-Disubstituted trans-epoxides were found to be excellent, selective substrates for the cytosolic epoxide hydrolase, while 1,2-cis-epoxides were poorly hydrated

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