277037
(1R,2R)-(+)-1-Phenylpropylene oxide
97%
Synonym(s):
(2R,3R)-(+)-2-Methyl-3-phenyloxirane
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About This Item
Empirical Formula (Hill Notation):
C9H10O
CAS Number:
Molecular Weight:
134.18
MDL number:
UNSPSC Code:
12352005
PubChem Substance ID:
NACRES:
NA.22
Assay
97%
form
liquid
optical activity
[α]20/D +110°, neat
optical purity
ee: 99% (GLC)
refractive index
n20/D 1.518 (lit.)
bp
201-207 °C (lit.)
density
1.006 g/mL at 25 °C (lit.)
SMILES string
C[C@H]1O[C@@H]1c2ccccc2
InChI
1S/C9H10O/c1-7-9(10-7)8-5-3-2-4-6-8/h2-7,9H,1H3/t7-,9+/m1/s1
InChI key
YVCOJTATJWDGEU-APPZFPTMSA-N
Application
Chiral building block. Tool for studying enzyme hydrolysis rates.
Signal Word
Warning
Hazard Statements
Precautionary Statements
Hazard Classifications
Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3
Target Organs
Respiratory system
Storage Class Code
10 - Combustible liquids
WGK
WGK 3
Flash Point(F)
156.2 °F - closed cup
Flash Point(C)
69 °C - closed cup
Personal Protective Equipment
dust mask type N95 (US), Eyeshields, Gloves
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B D Hammock et al.
Biochemical pharmacology, 32(7), 1155-1164 (1983-04-01)
The initial rates of hydration of sixteen epoxides in the presence of cytosolic and microsomal fractions of mouse liver were determined. 1,2-Disubstituted trans-epoxides were found to be excellent, selective substrates for the cytosolic epoxide hydrolase, while 1,2-cis-epoxides were poorly hydrated
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