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277142

1-Bromo-2-methyl-1-propene

98%

Synonym(s):

Isocrotyl bromide

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About This Item

Linear Formula:
(CH3)2C=CHBr
CAS Number:
3017-69-4
Molecular Weight:
135.00
UNSPSC Code:
12352100
NACRES:
NA.22
PubChem Substance ID:
24856737
MDL number:
MFCD00009885
Beilstein/REAXYS Number:
1733844
Assay:
98%
Form:
liquid
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Quality Segment

assay

98%

form

liquid

refractive index

n20/D 1.462 (lit.)

bp

92 °C (lit.)

density

1.318 g/mL at 25 °C (lit.)

functional group

alkyl halide, bromo

storage temp.

2-8°C

SMILES string

C\C(C)=C\Br

InChI

1S/C4H7Br/c1-4(2)3-5/h3H,1-2H3

InChI key

DEFNUDNHTUZJAL-UHFFFAOYSA-N

Application

1-Bromo-2-methyl-1-propene has been used in:
  • preparation of esters of 2,4-dienoic acids via palladium catalyzed reaction with methyl acrylate in the presence of triethylamine
  • total synthesis of ocular age pigment, A2-E
  • synthesis of 3-nor-geraniol [2H2]

Other Notes

May darken in storage

Pictograms

FlameExclamation mark
GHS02,GHS07

Signal Word

Danger

Hazard Classifications

Eye Irrit. 2 - Flam. Liq. 2 - Skin Irrit. 2 - STOT SE 3

Target Organs

Respiratory system

Storage Class

3 - Flammable liquids

WGK

WGK 3

Flash Point (°F)

44.6 °F - closed cup

Flash Point (°C)

7 °C - closed cup

PPE (personal protective equipment)

Eyeshields, Faceshields, Gloves, type ABEK (EN14387) respirator filter

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