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Merck
CN

280429

(三苯基膦)乙腈

97%

别名:

(氰亚甲基)三苯基膦

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关于此项目

线性分子式:
(C6H5)3P=CHCN
化学文摘社编号:
分子量:
301.32
NACRES:
NA.22
PubChem Substance ID:
UNSPSC Code:
12352002
EC Number:
240-689-7
MDL number:
Assay:
97%
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Quality Segment

assay

97%

reaction suitability

reaction type: C-C Bond Formation

mp

189-195 °C (lit.)

functional group

nitrile, phosphine

SMILES string

N#CC=P(c1ccccc1)(c2ccccc2)c3ccccc3

InChI

1S/C20H16NP/c21-16-17-22(18-10-4-1-5-11-18,19-12-6-2-7-13-19)20-14-8-3-9-15-20/h1-15,17H

InChI key

APISVOVOJVZIBA-UHFFFAOYSA-N

Application

由羰基化合物制备 α,β-不饱和腈的 Wittig 试剂。
Reactant for
  • Preparation of antitrypanosomal activity
  • Direct Michael addition of alkenes
  • Synthesis of 1,6-enynes
  • Beta-umpolung addition of nucleophiles to activated disubstituted alkyl allenes
  • Stereoselective analysis of β-homoproline derivatives
  • Stereoselective olefination of N-sulfonyl imines
  • Palladacycle mediated synthesis of cyano-functionalized chiral diphosphines
  • Horner-Wadsworth-Emmons reactions


pictograms

Exclamation mark

signalword

Warning

Hazard Classifications

Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3

target_organs

Respiratory system

存储类别

11 - Combustible Solids

wgk

WGK 3

flash_point_f

Not applicable

flash_point_c

Not applicable

ppe

dust mask type N95 (US), Eyeshields, Gloves



历史批次信息供参考:

分析证书(COA)

Lot/Batch Number

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