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Merck
CN

282316

Perfluoro-1,3-dimethylcyclohexane

technical grade, 80%

Synonym(s):

Decafluoro-1,3-bis(trifluoromethyl)cyclohexane, Hexadecafluoro-1,3-dimethylcyclohexane, Hexadecafluoro-1,3-dimethylcyclohexane (cis+trans)

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About This Item

Linear Formula:
C6F10(CF3)2
CAS Number:
335-27-3
Molecular Weight:
400.06
UNSPSC Code:
12352100
NACRES:
NA.22
PubChem Substance ID:
24857038
EC Number:
206-386-9
Beilstein/REAXYS Number:
2064147
MDL number:
MFCD00001469

Key Documents

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Product Name

Perfluoro-1,3-dimethylcyclohexane, technical grade, 80%

InChI key

LOQGSOTUHASIHI-UHFFFAOYSA-N

InChI

1S/C8F16/c9-1(7(19,20)21)3(11,12)2(10,8(22,23)24)5(15,16)6(17,18)4(1,13)14

SMILES string

FC(F)(F)C1(F)C(F)(F)C(F)(F)C(F)(F)C(F)(C(F)(F)F)C1(F)F

grade

technical grade

vapor density

14 (vs air)

assay

80%

form

liquid

refractive index

n20/D 1.3 (lit.)

bp

101-102 °C (lit.)

mp

−55 °C (lit.)

density

1.828 g/mL at 25 °C (lit.)

functional group

fluoro

Quality Level

100

Related Categories

Application

Perfluoro-1,3-dimethylcyclohexane has been used in:
  • the preparation of amorphous fluorocarbon films by plasma polymerization
  • hydroformylation of linear terminal alkenes using rhodium based catalysts under fluorous biphasic conditions in the presence and absence of toluene

General description

Quenching of the second excited singlet state of xanthione in inert, nonpolar perfluoro-1,3-dimethylcyclohexane has been studied using picosecond time-resolved fluorescence decay methods.

pictograms

Exclamation mark
GHS07

signalword

Warning

Hazard Classifications

Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3

target_organs

Respiratory system

Storage Class

10 - Combustible liquids

wgk

WGK 3

flash_point_f

Not applicable

flash_point_c

Not applicable

ppe

Eyeshields, Gloves, type ABEK (EN14387) respirator filter

Regulatory Information

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Certificates of Analysis (COA)

Lot/Batch Number
MKCT5933
MKCP5660
MKBF1780V
MKBC0791
07708BH

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Meagan M Gadzuk-Shea et al.
The journal of physical chemistry. B, 122(43), 9947-9955 (2018-10-24)
Understanding the structures of proteins in the gas phase is essential for using gas-phase measurements to infer the properties of proteins in solution. Using serum albumin as a model, this study aims to expand our understanding of this relationship for
Electrical and optical properties of amorphous fluorocarbon films prepared by plasma polymerization of perfluoro-1, 3-dimethylcyclohexane.
Weber A, et al.
Journal of Vacuum Science & Technology. A, Vacuum, Surfaces, And Films, 16(4), 2120-2124 (1998)
Transient effects in the fluorescence quenching of xanthione in perfluoro-1, 3-dimethylcyclohexane.
Maciejewski A, et al.
International Journal of Radiation Applications and Instrumentation, Part B: Nuclear Medicine and Biology, 39(1), 155-158 (1992)
Hydroformylation in perfluorinated solvents; improved selectivity, catalyst retention and product separation.
<BIG>Foster DF, et al. </BIG>
Tetrahedron, 58(20), 3901-3910 (2002)
Antonelle Pardo et al.
Journal of chromatography. A, 1364, 128-139 (2014-09-10)
Molecularly imprinted polymers (MIPs) based on quercetin and synthesized by either bulk, precipitation or suspension polymerization were characterized in terms of size and shape by scanning electron microscopy (SEM) and transmission electron microscopy (TEM). After a study of rebinding protocols

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