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282782

Platinum(II) acetylacetonate

97%

Synonym(s):

2,4-Pentanedione platinum(II) derivative, Pt(acac)2

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About This Item

Linear Formula:
Pt(C5H7O2)2
CAS Number:
15170-57-7
Molecular Weight:
393.29
UNSPSC Code:
12352103
NACRES:
NA.23
PubChem Substance ID:
24857069
EC Number:
239-223-5
Beilstein/REAXYS Number:
4136189
MDL number:
MFCD00000028
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Quality Segment

product line

Sol-Gel Precursors

assay

97%

form

solid

reaction suitability

core: platinum, reagent type: inorganic catalyst

mp

249-252 °C (lit.)

SMILES string

CC(=O)\C=C(\C)O[Pt]O\C(C)=C/C(C)=O

InChI

1S/2C5H8O2.Pt/c2*1-4(6)3-5(2)7;/h2*3,6H,1-2H3;/q;;+2/p-2/b2*4-3-;

InChI key

KLFRPGNCEJNEKU-FDGPNNRMSA-L

General description

Platinum(II)acetylacetonate is widely used as a Ptsource and precursor in the preparation of nanocatalysts and films. It is alsoused as a catalyst in N-allylation reactions.

Application

Platinum(II)acetylacetonate can be used as an efficient catalyst:
  • In the preparation of N-allylanilines by the direct use of allylic alcohols. Anilines with electron-donating groups give good yields.
  • For selective N-allylation of 2,3-disubstituted indoles in water.
Pt-loaded ZnO thick films can be prepared by flame spray pyrolysis method using zinc naphthenate and platinum(II) acetylacetonate as precursors. These sensing films can be used for acetylene detection and show good selectivity towards carbon monoxide, hydrogen, and methane.

It can be used as a starting material in the preparation of platinum-lead nanoparticles supported on carbon. The PtPb/C catalyst exhibits enhanced electrochemical activity towards methanol and formic acid oxidation.

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Pictograms

Health hazardExclamation mark
GHS08,GHS07

Signal Word

Warning

Hazard Classifications

Acute Tox. 4 Dermal - Acute Tox. 4 Inhalation - Acute Tox. 4 Oral - Eye Irrit. 2 - Repr. 2 - Skin Irrit. 2 - STOT SE 3

Target Organs

Respiratory system

Storage Class

11 - Combustible Solids

Flash Point (°F)

Not applicable

Flash Point (°C)

Not applicable

PPE (personal protective equipment)

Eyeshields, Gloves, type P3 (EN 143) respirator cartridges

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