283207
Magnesium bis(monoperoxyphthalate) hexahydrate
80%, technical grade
Synonym(s):
MMPP
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About This Item
Linear Formula:
(HO2CC6H4CO3)2Mg·6H2O
Molecular Weight:
494.64
NACRES:
NA.22
PubChem Substance ID:
UNSPSC Code:
12352002
EC Number:
279-013-0
MDL number:
Assay:
80%
grade
technical grade
Quality Segment
assay
80%
reaction suitability
reagent type: oxidant
greener alternative product characteristics
Designing Safer Chemicals
Learn more about the Principles of Green Chemistry.
sustainability
Greener Alternative Product
mp
93 °C (dec.) (lit.)
functional group
hydroperoxide
greener alternative category
SMILES string
O.O.O.O.O.O.OOC(=O)c1ccccc1C(=O)O[Mg]OC(=O)c2ccccc2C(=O)OO
InChI
1S/2C8H6O5.Mg.6H2O/c2*9-7(10)5-3-1-2-4-6(5)8(11)13-12;;;;;;;/h2*1-4,12H,(H,9,10);;6*1H2/q;;+2;;;;;;/p-2
InChI key
WWOYCMCZTZTIGU-UHFFFAOYSA-L
General description
We are committed to bringing you Greener Alternative Products, which adhere to one or more of The 12 Principles of Greener Chemistry. This product MMPP is an alternative to widely used oxidant MCPBA as it is cheap, stable in the solid state, safer in handling and easier to use and thus aligns with the principle "Designing Safer Chemicals". For more information see the below articles.
Magnesium bis(monoperoxyphthalate) hexahydrate as mild and efficient oxidant for the synthesis of selenones.
Magnesium Bis(monoperoxyphthalate) Hexahydrate (MMPP).
Highly efficient epoxidation of unsaturated steroids using magnesium bis(monoperoxyphthalate) hexahydrate.
Magnesium bis(monoperoxyphthalate) hexahydrate as mild and efficient oxidant for the synthesis of selenones.
Magnesium Bis(monoperoxyphthalate) Hexahydrate (MMPP).
Highly efficient epoxidation of unsaturated steroids using magnesium bis(monoperoxyphthalate) hexahydrate.
Application
A safer, greener oxidizing reagent that is a suitable replacement for peroxycarboxylic acids and is capable of effecting many types of oxidation reactions.
Oxidation Reactions Using Magnesium Monoperphthalate: A Comparison with m-Chloroperoxybenzoic Acid
Oxidation Reactions Using Magnesium Monoperphthalate: A Comparison with m-Chloroperoxybenzoic Acid
Reagent for:
- Trans-diaxial hydroxylation under bismuth(III) triflate catalyst
- Oxidation rections under mild conditions
- Epoxidation of unsaturated steroids
- Synthesis of ring-B oxygenated steroids as anticancer agents
signalword
Danger
hcodes
Hazard Classifications
Acute Tox. 4 Inhalation - Eye Dam. 1 - Org. Perox. E - Skin Corr. 1C
Storage Class
5.2 - Organic peroxides and self-reacting hazardous materials
flash_point_f
Not applicable
flash_point_c
Not applicable
ppe
dust mask type N95 (US), Eyeshields, Gloves
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