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283673

Copper(II) trifluoromethanesulfonate

98%

greener alternative

Greener Alternative

Synonym(s):

Cu(OTf)2, Copper(II) triflate, Cupric trifluoromethanesulfonate, Trifluoromethanesulfonic acid copper(II) salt

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About This Item

Linear Formula:
(CF3SO3)2Cu
CAS Number:
Molecular Weight:
361.68
UNSPSC Code:
12161600
NACRES:
NA.22
PubChem Substance ID:
EC Number:
252-300-8
Beilstein/REAXYS Number:
4028198
MDL number:
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Quality Segment

assay

98%

reaction suitability

core: copper, reagent type: catalyst

greener alternative product characteristics

Catalysis
Learn more about the Principles of Green Chemistry.

sustainability

Greener Alternative Product

mp

≥300 °C

greener alternative category

SMILES string

FC(F)(F)S(=O)(=O)O[Cu]OS(=O)(=O)C(F)(F)F

InChI

1S/2CHF3O3S.Cu/c2*2-1(3,4)8(5,6)7;/h2*(H,5,6,7);/q;;+2/p-2

InChI key

SBTSVTLGWRLWOD-UHFFFAOYSA-L

General description

We are committed to bringing you Greener Alternative Products, which adhere to one or more of the 12 Principles of Green Chemistry. This catalyst promotes Friedel-Crafts reactions, aldol condensations, and cycloadditions with exceptional selectivity and water tolerance. Its compatibility with aqueous media eliminates anhydrous conditions and enables sustainable synthesis. Click here for more information.

Application

Catalyzes the efficient addition of trimethylsilyl cyanide to carbonyl compounds.
Catalyst for:
  • Mannich condensation
  • Annulative amination
  • Friedel-Crafts reaction
  • Henry reaction
  • Hypervalent iodine reagent-mediated preparation of carbazoles
  • Intramolecular oxidative C-N bond formation for the synthesis of carbazoles


Storage Class

11 - Combustible Solids

flash_point_f

Not applicable

flash_point_c

Not applicable

ppe

Eyeshields, Faceshields, Gloves, type P3 (EN 143) respirator cartridges



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