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283673

Copper(II) trifluoromethanesulfonate

98%

Synonym(s):

Cu(OTf)2, Copper(II) triflate, Cupric trifluoromethanesulfonate, Trifluoromethanesulfonic acid copper(II) salt

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About This Item

Linear Formula:
(CF3SO3)2Cu
CAS Number:
34946-82-2
Molecular Weight:
361.68
UNSPSC Code:
12161600
NACRES:
NA.22
PubChem Substance ID:
24857124
EC Number:
252-300-8
Beilstein/REAXYS Number:
4028198
MDL number:
MFCD00077492
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Quality Level

200

assay

98%

reaction suitability

core: copper, reagent type: catalyst

mp

≥300 °C

SMILES string

FC(F)(F)S(=O)(=O)O[Cu]OS(=O)(=O)C(F)(F)F

InChI

1S/2CHF3O3S.Cu/c2*2-1(3,4)8(5,6)7;/h2*(H,5,6,7);/q;;+2/p-2

InChI key

SBTSVTLGWRLWOD-UHFFFAOYSA-L

Application

Catalyzes the efficient addition of trimethylsilyl cyanide to carbonyl compounds.
Catalyst for:
  • Mannich condensation
  • Annulative amination
  • Friedel-Crafts reaction
  • Henry reaction
  • Hypervalent iodine reagent-mediated preparation of carbazoles
  • Intramolecular oxidative C-N bond formation for the synthesis of carbazoles

Storage Class

11 - Combustible Solids

flash_point_f

Not applicable

flash_point_c

Not applicable

ppe

Eyeshields, Faceshields, Gloves, type P3 (EN 143) respirator cartridges

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Certificates of Analysis (COA)

Lot/Batch Number
MKCZ1060
MKCX1338
0000408267
0000312266
0000408267

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Biswarup Chakraborty et al.
Chemistry, an Asian journal, 15(6), 852-859 (2020-02-06)
In the urge of designing noble metal-free and sustainable electrocatalysts for oxygen evolution reaction (OER), herein, a mineral Digenite Cu9 S5 has been prepared from a molecular copper(I) precursor, [{(PyHS)2 CuI (PyHS)}2 ](OTf)2 (1), and utilized as an anode material
Saravanan, P. et al.
Tetrahedron Letters, 39, 3823-3823 (1998)
Dario Formenti et al.
Chemical reviews, 119(4), 2611-2680 (2018-12-06)
The reduction of nitro compounds to the corresponding amines is one of the most utilized catalytic processes in the fine and bulk chemical industry. The latest development of catalysts with cheap metals like Fe, Co, Ni, and Cu has led
View All Related Papers

Global Trade Item Number

SKUGTIN
283673-5G04061826245996
283673-25G04061826245989