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293547

exo-2-Chloronorbornane

Name: <I>exo</I>-2-Chloronorbornane
Brand: ALDRICH

98%

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About This Item

Empirical Formula (Hill Notation):

C₇H₁₁Cl

CAS Number:

765-91-3

Molecular Weight:

130.62

NACRES:

NA.22

PubChem Substance ID:

24857665

UNSPSC Code:

12352100

MDL number:

MFCD00167585

Assay:

98%

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Properties

assay

98%

refractive index

n20/D 1.4854 (lit.)

bp

66-66.5 °C/30 mmHg (lit.)

density

1.06 g/mL at 25 °C (lit.)

functional group

chloro

SMILES string

ClC1C[C@@H]2CC[C@H]1C2

InChI

1S/C7H11Cl/c8-7-4-5-1-2-6(7)3-5/h5-7H,1-4H2/t5-,6+,7?/m1/s1

InChI key

PJWBUKHIZPKRJF-JEAXJGTLSA-N

Description

General description

exo-2-Chloronorbornane undergoes amination with trichloramine-aluminum chloride to yield 2-azabicyclo[3.2.1]octane, small amounts of the 3-isomer and exo-2-aminonorbornane.

Application

exo-2-Chloronorbornane has been employed as reagent during Friedel-Crafts alkylation of benzene and substituted benzenes with tin(IV) chloride or aluminium trichloride.

pictograms

GHS02

signalword

Warning

hcodes

H226

Hazard Classifications

Flam. Liq. 3

Storage Class

3 - Flammable liquids

wgk

WGK 3

flash_point_f

111.2 °F - closed cup

flash_point_c

44 °C - closed cup

ppe

Eyeshields, Faceshields, Gloves, type ABEK (EN14387) respirator filter

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