29511
(S)-(−)-(6,6′-Dimethoxybiphenyl-2,2′-diyl)bis(diphenylphosphine)
≥97%, optical purity ee: ≥99%
Synonym(s):
(S)-(−)-2,2′-Bis(diphenylphosphino)-6,6′-dimethoxy-1,1′-biphenyl, (S)-(−)-MeO-BIPHEP, SL-A101-2
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About This Item
Product Name
(S)-(−)-(6,6′-Dimethoxybiphenyl-2,2′-diyl)bis(diphenylphosphine), ≥97%, optical purity ee: ≥99%
InChI
1S/C38H32O2P2/c1-39-33-25-15-27-35(41(29-17-7-3-8-18-29)30-19-9-4-10-20-30)37(33)38-34(40-2)26-16-28-36(38)42(31-21-11-5-12-22-31)32-23-13-6-14-24-32/h3-28H,1-2H3
InChI key
KRJVQCZJJSUHHO-UHFFFAOYSA-N
SMILES string
COc1cccc(P(c2ccccc2)c3ccccc3)c1-c4c(OC)cccc4P(c5ccccc5)c6ccccc6
assay
≥97%
optical purity
ee: ≥99%
greener alternative product characteristics
Catalysis
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sustainability
Greener Alternative Product
functional group
phosphine
greener alternative category
Quality Level
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Application
- C–C coupling reactions
- Ligand for palladium-catalyzed intramolecular allylic alkylation of unsaturated amides
- Enantioselective hydrogenation of a-amino-ß-keto ester hydrochlorides catalyzed by an iridium complex
- Asymmetric hydrogenation of aromatic ketones
Asymmetric Synthesis of (S)-3-Amino-4-methoxy-butan-1-ol by Way of Reductive Amination
General description
Packaging
Storage Class
11 - Combustible Solids
wgk
WGK 3
flash_point_f
Not applicable
flash_point_c
Not applicable
ppe
Eyeshields, Gloves, type N95 (US)
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