29570
1,3-Cyclooctadiene
technical, ≥95% (GC)
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About This Item
Empirical Formula (Hill Notation):
C8H12
CAS Number:
Molecular Weight:
108.18
UNSPSC Code:
12352100
NACRES:
NA.22
PubChem Substance ID:
EC Number:
216-929-1
Beilstein/REAXYS Number:
2321915
MDL number:
Assay:
≥95% (GC)
Product Name
1,3-Cyclooctadiene, technical, ≥95% (GC)
InChI key
RRKODOZNUZCUBN-CCAGOZQPSA-N
InChI
1S/C8H12/c1-2-4-6-8-7-5-3-1/h1-4H,5-8H2/b3-1-,4-2-
SMILES string
C1CCC=CC=CC1
grade
technical
assay
≥95% (GC)
refractive index
n20/D 1.494
bp
142-144 °C (lit.)
density
0.873 g/mL at 20 °C (lit.)
storage temp.
2-8°C
Quality Level
Related Categories
Application
1,3-Cyclooctadiene has been used in the preparation of 2-cyclooct-2-en-1-yl-1,3-cyclooctadiene, a novel bicyclic triene.
General description
Enantiodifferentiating geometrical photoisomerizations of (Z,Z)-1,3-cyclooctadiene was studied using "cyclodextrin nanosponge", as a supramolecular sensitizing host. Dendrimer-encapsulated Pd-Rh bimetallic nanoparticle catalyzed partial hydrogenation of 1,3-cyclooctadiene has been reported.
signalword
Danger
hcodes
Hazard Classifications
Asp. Tox. 1 - Flam. Liq. 3
Storage Class
3 - Flammable liquids
wgk
WGK 3
flash_point_f
77.0 °F - closed cup
flash_point_c
25 °C - closed cup
ppe
Eyeshields, Faceshields, Gloves, type ABEK (EN14387) respirator filter
Regulatory Information
危险化学品
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Partial hydrogenation of 1, 3-cyclooctadiene using dendrimer-encapsulated Pd-Rh bimetallic nanoparticles.
Chung Y-M and Rhee H-K.
J. Mol. Catal. A: Chem., 206(1), 291-298 (2003)
Wenting Liang et al.
Beilstein journal of organic chemistry, 8, 1305-1311 (2012-09-29)
Enantiodifferentiating geometrical photoisomerizations of (Z)-cyclooctene and (Z,Z)-1,3-cyclooctadiene were performed by using the pyromellitate-linked cyclodextrin network polymer, termed "cyclodextrin nanosponge (CDNS)", as a supramolecular sensitizing host. The photochirogenic behavior of the nanosponges incorporating β- or γ-cyclodextrin was significantly different from that
Metal-mediated dimerization of 1, 3-cyclooctadiene to 2-cyclooct-2-en-1-yl-1, 3-cyclooctadiene: a novel bicyclic triene.
Debad JD, et al.
Journal of the American Chemical Society, 115(5), 2051-2052 (1993)
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