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296643

(R)-(−)-sec-Butylamine

Name: (<I>R</I>)-(−)-<I>sec</I>-Butylamine
Brand: ALDRICH

99%

Synonym(s):

(R)-(−)-2-Aminobutane

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About This Item

Linear Formula:

C₂H₅CH(NH₂)CH₃

CAS Number:

13250-12-9

Molecular Weight:

73.14

UNSPSC Code:

12352116

NACRES:

NA.22

PubChem Substance ID:

24857863

EC Number:

236-232-6

Beilstein/REAXYS Number:

1718761

MDL number:

MFCD00064416

Assay:

99%

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Quality Level

200

assay

99%

optical activity

[α]19/D −7.5°, neat

refractive index

n20/D 1.393 (lit.)

bp

63 °C (lit.)

density

0.72 g/mL at 25 °C (lit.)

functional group

amine

SMILES string

CC[C@@H](C)N

InChI

1S/C4H11N/c1-3-4(2)5/h4H,3,5H2,1-2H3/t4-/m1/s1

InChI key

BHRZNVHARXXAHW-SCSAIBSYSA-N

Related Categories

Catalysts

Chiral Catalysts & Ligands

Application

(R)-(−)-sec-Butylamine can be used:

To prepare (R)-(−)-sec-butylbis(2-hydroxyethyl)amine, an intermediate for the synthesis of aminodiphosphine ligands.
As a substrate to demonstrate the stereochemistry of Mitsunobu reaction in the synthesis of secondary amines.
As a model compound in the study of singlet-triplet transitions in circular dichroism.

Packaging

Bottomless glass bottle. Contents are inside inserted fused cone.

pictograms

GHS02,GHS05,GHS07,GHS09

signalword

Danger

hcodes

H225,H302 + H332,H314,H410

pcodes

P210 - P273 - P280 - P303 + P361 + P353 - P304 + P340 + P310 - P305 + P351 + P338

Hazard Classifications

Acute Tox. 4 Inhalation - Acute Tox. 4 Oral - Aquatic Acute 1 - Aquatic Chronic 1 - Eye Dam. 1 - Flam. Liq. 2 - Skin Corr. 1A

Storage Class

3 - Flammable liquids

wgk

WGK 3

flash_point_f

-2.2 °F - closed cup

flash_point_c

-19 °C - closed cup

ppe

Faceshields, Gloves, Goggles

Regulatory Information

危险化学品

农药列管产品

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Detection of singlet-triplet transitions in circular dichroism. A study of 2-aminobutane

Basil A and Gedanken A

Journal of the American Chemical Society, 111(26), 9237-9238 (1989)

Stereospecific synthesis of secondary amines by the Mitsunobu reaction

Edwards ML, et al.

Tetrahedron Letters, 31(24), 3417-3420 (1990)

Synthesis of the New Chiral (R)-and (S)-Aminodiphosphine Ligands sec-Butylbis (2-(diphenylphosphino) ethyl) amine, sec-Butylbis (2-(dicyclohexylphosphino) ethyl) amine, and (alpha-Methylbenzyl) bis (2-(dicyclohexylphosphino) ethyl) amine and Their Organom

Bianchini C, et al.

Organometallics, 16(20), 4403-4414 (1997)

Global Trade Item Number

SKU	GTIN
296643-1G	04061837639753
296643-250MG	04061826656440

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