297917
Methyl 2,2-dichloro-2-methoxyacetate
97%
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About This Item
Linear Formula:
Cl2C(OCH3)CO2CH3
CAS Number:
Molecular Weight:
172.99
NACRES:
NA.22
PubChem Substance ID:
UNSPSC Code:
12352100
MDL number:
Assay:
97%
InChI
1S/C4H6Cl2O3/c1-8-3(7)4(5,6)9-2/h1-2H3
SMILES string
COC(=O)C(Cl)(Cl)OC
InChI key
FWIGIASHGJFYOL-UHFFFAOYSA-N
assay
97%
refractive index
n20/D 1.45 (lit.)
bp
179-181 °C (lit.)
density
1.36 g/mL at 25 °C (lit.)
functional group
chloro, ester, ether
Quality Level
Related Categories
Application
Methyl 2,2-dichloro-2-methoxyacetate was used in the preparation of methyl (Z)-α-methoxyacrylates via stereospecific two-carbon homologation of aldehydes under Barbier conditions.
signalword
Danger
hcodes
Hazard Classifications
Skin Corr. 1B - STOT SE 3
target_organs
Respiratory system
Storage Class
8A - Combustible corrosive hazardous materials
wgk
WGK 3
flash_point_f
195.8 °F - closed cup
flash_point_c
91 °C - closed cup
ppe
Faceshields, Gloves, Goggles, type ABEK (EN14387) respirator filter
Regulatory Information
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Stereoselective synthesis of methyl (Z)-a-methoxyacrylates via two-carbon homologation of aldehydes.
Baati R, et al.
Tetrahedron Letters, 50(4), 402-405 (2009)
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