298441
Chloroborane methyl sulfide complex
Synonym(s):
Boron monochloride methyl sulfide complex, Chloro(dimethyl sulfide)dihydroboron, Monochloroborane-dimethyl sulfide, monoChloroborane methyl sulfide complex
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About This Item
Linear Formula:
(CH3)2S·BH2Cl
CAS Number:
Molecular Weight:
110.41
NACRES:
NA.22
PubChem Substance ID:
UNSPSC Code:
12352101
MDL number:
Quality Segment
reaction suitability
reagent type: reductant
density
1.059 g/mL at 25 °C (lit.)
functional group
thioether
SMILES string
C[S+](C)[BH2-]Cl
InChI
1S/C2H8BClS/c1-5(2)3-4/h3H2,1-2H3
InChI key
CUKLQTNDSCOWTI-UHFFFAOYSA-N
Application
Reactant for:
- Substitution reactions
- Boronation reactions
- Preparation of diborylamines
- Preparation of unsymmetrical borafluorenes via low-temperature carbon-hydrogen activation reactions
- Asymmetrical aldol reactions with a-chiral aldehydes
- Addition reaction with α-pinene
Reagent for hydroboration and synthesis of chlorodialkylboranes.
signalword
Danger
hcodes
Hazard Classifications
Flam. Liq. 3 - Skin Corr. 1B
supp_hazards
Storage Class
3 - Flammable liquids
wgk
WGK 3
flash_point_f
75.2 °F - closed cup
flash_point_c
24 °C - closed cup
ppe
Faceshields, Gloves, Goggles, type ABEK (EN14387) respirator filter
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