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301248

Tris[2-(2-methoxyethoxy)ethyl]amine

Name: Tris[2-(2-methoxyethoxy)ethyl]amine
Brand: ALDRICH

95%

Synonym(s):

TDA-1, Tris(3,6-dioxaheptyl)amine

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About This Item

Linear Formula:

(CH₃OCH₂CH₂OCH₂CH₂)₃N

CAS Number:

70384-51-9

Molecular Weight:

323.43

UNSPSC Code:

12352100

NACRES:

NA.22

PubChem Substance ID:

24858174

EC Number:

274-590-5

Beilstein/REAXYS Number:

2369296

MDL number:

MFCD00010748

Assay:

95%

Form:

liquid

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Properties

Quality Level

200

assay

95%

form

liquid

refractive index

n20/D 1.4486 (lit.)

density

1.011 g/mL at 25 °C (lit.)

functional group

amine, ether

SMILES string

COCCOCCN(CCOCCOC)CCOCCOC

InChI

1S/C15H33NO6/c1-17-10-13-20-7-4-16(5-8-21-14-11-18-2)6-9-22-15-12-19-3/h4-15H2,1-3H3

InChI key

XGLVDUUYFKXKPL-UHFFFAOYSA-N

Description

Application

Tris[2-(2-methoxyethoxy)ethyl]amine was used:

in oxidation of arylmethanols under phase-transfer conditions
as cryptand during phase-transfer glycosylation of 2-amino-4-methoxy-7H-pyrrolo[2,3-d]pyrimidine
as phase-transfer catalyst in synthesis of 1,3-dideaza-2′-deoxyadenosine and related benzimidazole 2′-deoxyribonucleosides

pictograms

GHS05

signalword

Danger

hcodes

H314

pcodes

P280 - P303 + P361 + P353 - P304 + P340 + P310 - P305 + P351 + P338 - P363 - P405

Hazard Classifications

Eye Dam. 1 - Skin Corr. 1C

Storage Class

8A - Combustible corrosive hazardous materials

wgk

WGK 2

flash_point_f

323.6 °F - closed cup

flash_point_c

162 °C - closed cup

ppe

Faceshields, Gloves, Goggles, type ABEK (EN14387) respirator filter

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Liquid-liquid and solid-liquid phase-transfer glycosylation of pyrrolo [2, 3-d] pyrimidines: stereospecific synthesis of 2-deoxy-?-D-ribofuranosides related to 2'-deoxy-7-carbaguanosine.

Seela F, et al.

Journal of the Chemical Society. Perkin Transactions 1, 3, 697-702 (1998)

Phase-Transfer Catalysed Permanganate Oxidations Using Tris [2-(2-Methoxyethoxy) Ethyl] Amine (Tda-1).

Mckillop A and Mills LS.

Synthetic Communications, 17(6), 647-655 (1987)

Stereoselective glycosylation of nitrobenzimidazole anions: synthesis of 1, 3-dideaza-2'-deoxyadenosine and related 2'-deoxyribofuranosides.

Seela F and Bourgeois W.

Synthesis, 12, 912-918 (1989)

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Global Trade Item Number

SKU	GTIN
301248-500G	04061837014666
301248-100G	04061826665251
301248-5G	04061837007835