301248
Tris[2-(2-methoxyethoxy)ethyl]amine
95%
Synonym(s):
TDA-1, Tris(3,6-dioxaheptyl)amine
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About This Item
Linear Formula:
(CH3OCH2CH2OCH2CH2)3N
CAS Number:
Molecular Weight:
323.43
UNSPSC Code:
12352100
NACRES:
NA.22
PubChem Substance ID:
EC Number:
274-590-5
Beilstein/REAXYS Number:
2369296
MDL number:
Assay:
95%
Form:
liquid
InChI key
XGLVDUUYFKXKPL-UHFFFAOYSA-N
InChI
1S/C15H33NO6/c1-17-10-13-20-7-4-16(5-8-21-14-11-18-2)6-9-22-15-12-19-3/h4-15H2,1-3H3
SMILES string
COCCOCCN(CCOCCOC)CCOCCOC
assay
95%
form
liquid
refractive index
n20/D 1.4486 (lit.)
density
1.011 g/mL at 25 °C (lit.)
functional group
amine, ether
Quality Level
Related Categories
Application
Tris[2-(2-methoxyethoxy)ethyl]amine was used:
- in oxidation of arylmethanols under phase-transfer conditions
- as cryptand during phase-transfer glycosylation of 2-amino-4-methoxy-7H-pyrrolo[2,3-d]pyrimidine
- as phase-transfer catalyst in synthesis of 1,3-dideaza-2′-deoxyadenosine and related benzimidazole 2′-deoxyribonucleosides
signalword
Danger
hcodes
Hazard Classifications
Eye Dam. 1 - Skin Corr. 1C
Storage Class
8A - Combustible corrosive hazardous materials
wgk
WGK 2
flash_point_f
323.6 °F - closed cup
flash_point_c
162 °C - closed cup
ppe
Faceshields, Gloves, Goggles, type ABEK (EN14387) respirator filter
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Phase-Transfer Catalysed Permanganate Oxidations Using Tris [2-(2-Methoxyethoxy) Ethyl] Amine (Tda-1).
Mckillop A and Mills LS.
Synthetic Communications, 17(6), 647-655 (1987)
Liquid-liquid and solid-liquid phase-transfer glycosylation of pyrrolo [2, 3-d] pyrimidines: stereospecific synthesis of 2-deoxy-?-D-ribofuranosides related to 2'-deoxy-7-carbaguanosine.
Seela F, et al.
Journal of the Chemical Society. Perkin Transactions 1, 3, 697-702 (1998)
Stereoselective glycosylation of nitrobenzimidazole anions: synthesis of 1, 3-dideaza-2'-deoxyadenosine and related 2'-deoxyribofuranosides.
Seela F and Bourgeois W.
Synthesis, 12, 912-918 (1989)
Falk Kunkel et al.
Molecules (Basel, Switzerland), 20(11), 20805-20822 (2015-11-28)
DNA methyltransferases (MTases) catalyze the transfer of the activated methyl group of the cofactor S-adenosyl-l-methionine (AdoMet or SAM) to the exocyclic amino groups of adenine or cytosine or the C5 ring atom of cytosine within specific DNA sequences. The DNA
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