301612
9-Anthraldehyde oxime, predominantly syn
99%
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About This Item
Empirical Formula (Hill Notation):
C15H11NO
CAS Number:
Molecular Weight:
221.25
NACRES:
NA.22
PubChem Substance ID:
UNSPSC Code:
12352100
MDL number:
Assay:
99%
InChI
1S/C15H11NO/c17-16-10-15-13-7-3-1-5-11(13)9-12-6-2-4-8-14(12)15/h1-10,17H/b16-10+
SMILES string
O\N=C\c1c2ccccc2cc3ccccc13
InChI key
HLGMTCSSRBPNOQ-MHWRWJLKSA-N
assay
99%
mp
162-164 °C (lit.)
functional group
amine, oxime
Application
9-Anthraldehyde oxime was used in preparation of new triosmium cluster [Os3(CO)11(C14H9CN)].
General description
Gallium triflate catalyzed dehydration of 9-anthraldehyde oxime to nitrile is reported.
signalword
Warning
hcodes
Hazard Classifications
Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3
target_organs
Respiratory system
Storage Class
11 - Combustible Solids
wgk
WGK 3
flash_point_f
Not applicable
flash_point_c
Not applicable
ppe
dust mask type N95 (US), Eyeshields, Gloves
Regulatory Information
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Gallium (III) triflate catalyzed dehydration of aldoximes.
Yan P, et al.
Catalysis Letters, 101(3), 141-143 (2005)
Synthesis and structural characterization of a triosmium carbonyl cluster containing a 9-anthracenecarbonitrile ligand derived from 9-anthraldehyde oxime.
Wong JS-Y, et al.
Inorganic Chemistry Communications, 6(6), 713-717 (2003)
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