301817
5,6-Dimethyl-1,10-phenanthroline
97%
Synonym(s):
5,6-Dimethyl-o-phenanthroline
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About This Item
Empirical Formula (Hill Notation):
C14H12N2
CAS Number:
Molecular Weight:
208.26
UNSPSC Code:
12352100
NACRES:
NA.22
PubChem Substance ID:
EC Number:
221-100-2
Beilstein/REAXYS Number:
160918
MDL number:
Product Name
5,6-Dimethyl-1,10-phenanthroline, 97%
InChI key
BRPQDJPJBCQFSR-UHFFFAOYSA-N
InChI
1S/C14H12N2/c1-9-10(2)12-6-4-8-16-14(12)13-11(9)5-3-7-15-13/h3-8H,1-2H3
SMILES string
Cc1c(C)c2cccnc2c3ncccc13
assay
97%
mp
266-269 °C (lit.)
Quality Level
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Application
5,6-Dimethyl-1,10-phenanthroline was employed as ligand in the preparation of:
- novel tetrahedral copper(I) mixed-ligand complexes
- mixed ligand Ru(II) complexes
- 5,6-bis(bromomethyl)-1,10-phenanthroline via bromination with N-bromosuccinimide
Storage Class
11 - Combustible Solids
wgk
WGK 3
flash_point_f
Not applicable
flash_point_c
Not applicable
ppe
Eyeshields, Gloves, type N95 (US)
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Self-assembled fullerene-derivative monolayers on a gold substrate using phenanthroline-Au interactions.
Dominguez O, et al.
Langmuir, 14(4), 821-824 (1998)
Valentina Gandin et al.
Journal of medicinal chemistry, 56(18), 7416-7430 (2013-08-24)
Novel tetrahedral copper(I) mixed-ligand complexes of the type [Cu(X)(N(∩)N)(PCN)], 3-10, where X = Cl or Br, N(∩)N = 2,2'-bipyridine (bipy), 1,10-phenanthroline (phen), 5,6-dimethyl-1,10-phenanthroline (dmp), and dipyrido-[3,2-d:2',3'-f]-quinoxaline (dpq), and PCN = tris-(2-cyanoethyl)phosphine, have been synthetized and characterized by NMR, ESI-MS, and
Mixed ligand ruthenium (II) complexes of 5, 6-dimethyl-1, 10-phenanthroline: the role of ligand hydrophobicity on DNA binding of the complexes.
Uma MP, et al.
Inorgorganica Chimica Acta, 359(14), 4601-4612 (2006)
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