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Merck
CN

303305

Bromodimethylborane

Synonym(s):

Dimethylboron bromide

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About This Item

Linear Formula:
(CH3)2BBr
CAS Number:
Molecular Weight:
120.78
PubChem Substance ID:
UNSPSC Code:
12352101
Beilstein/REAXYS Number:
1730828
MDL number:
Form:
liquid
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SMILES string

CB(C)Br

InChI

1S/C2H6BBr/c1-3(2)4/h1-2H3

InChI key

ABQPEYRVNHDPIO-UHFFFAOYSA-N

vapor pressure

10.4 psi ( 20 °C)

form

liquid

reaction suitability

reagent type: reductant

bp

31-32 °C (lit.)

mp

−129 °C (lit.)

density

1.238 g/mL at 25 °C (lit.)

storage temp.

2-8°C

Quality Level

pictograms

FlameCorrosion

signalword

Danger

hcodes

Hazard Classifications

Eye Dam. 1 - Pyr. Liq. 1 - Skin Corr. 1B

Storage Class

4.2 - Pyrophoric and self-heating hazardous materials

wgk

WGK 3

flash_point_f

No data available

flash_point_c

No data available

ppe

Faceshields, Gloves, Goggles

Regulatory Information

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Synlett, 171-171 (1991)
Tetrahedron, 48, 5831-5831 (1992)
Tetrahedron Letters, 28, 2225-2225 (1987)
D R Kodali
Journal of lipid research, 28(4), 464-469 (1987-04-01)
Optically active 1- or 3-acyl-sn-glycerols were synthesized from 2,3- or 1,2-isopropylidene-sn-glycerols, respectively. The 2,3- or 1,2-isopropylidene-sn-glycerols were condensed with appropriate long saturated or unsaturated fatty acids and the resulting acyl isopropylidene compounds were treated with dimethylboronbromide at - 50 degrees

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